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2,2′-Dimethoxy-6,6′-dinitrobiphenyl
In the title compound, C(14)H(12)N(2)O(6), the half molecule in the asymmetric unit of the cell is completed by a crystallographic twofold rotation axis, and the two benzene rings of the complete molecule make a dihedral angle of 60.5 (3)°. Furthermore, intermolecular weak C—H⋯O hydrogen bonds li...
Autores principales: | , , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2009
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2970430/ https://www.ncbi.nlm.nih.gov/pubmed/21577785 http://dx.doi.org/10.1107/S1600536809033790 |
Sumario: | In the title compound, C(14)H(12)N(2)O(6), the half molecule in the asymmetric unit of the cell is completed by a crystallographic twofold rotation axis, and the two benzene rings of the complete molecule make a dihedral angle of 60.5 (3)°. Furthermore, intermolecular weak C—H⋯O hydrogen bonds link adjacent molecules, forming a two-dimensional sheet. These sheets are stablized by face-to-face weak π–π contacts [centroid–centroid distance = 3.682 (1) Å] between the nearly parallel [dihedral angle = 0.12 (7)°] benzene rings of the neighboring molecules, resulting in a three-dimensional network. |
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