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2,2′-Dimeth­oxy-6,6′-dinitro­biphen­yl

In the title compound, C(14)H(12)N(2)O(6), the half mol­ecule in the asymmetric unit of the cell is completed by a crystallographic twofold rotation axis, and the two benzene rings of the complete mol­ecule make a dihedral angle of 60.5 (3)°. Furthermore, inter­molecular weak C—H⋯O hydrogen bonds li...

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Detalles Bibliográficos
Autores principales: Miao, Shao-Bin, Deng, Dong-Sheng, Liu, Xian-Ming, Ji, Bao-Ming
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2970430/
https://www.ncbi.nlm.nih.gov/pubmed/21577785
http://dx.doi.org/10.1107/S1600536809033790
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author Miao, Shao-Bin
Deng, Dong-Sheng
Liu, Xian-Ming
Ji, Bao-Ming
author_facet Miao, Shao-Bin
Deng, Dong-Sheng
Liu, Xian-Ming
Ji, Bao-Ming
author_sort Miao, Shao-Bin
collection PubMed
description In the title compound, C(14)H(12)N(2)O(6), the half mol­ecule in the asymmetric unit of the cell is completed by a crystallographic twofold rotation axis, and the two benzene rings of the complete mol­ecule make a dihedral angle of 60.5 (3)°. Furthermore, inter­molecular weak C—H⋯O hydrogen bonds link adjacent mol­ecules, forming a two-dimensional sheet. These sheets are stablized by face-to-face weak π–π contacts [centroid–centroid distance = 3.682 (1) Å] between the nearly parallel [dihedral angle = 0.12 (7)°] benzene rings of the neighboring mol­ecules, resulting in a three-dimensional network.
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spelling pubmed-29704302010-12-30 2,2′-Dimeth­oxy-6,6′-dinitro­biphen­yl Miao, Shao-Bin Deng, Dong-Sheng Liu, Xian-Ming Ji, Bao-Ming Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(14)H(12)N(2)O(6), the half mol­ecule in the asymmetric unit of the cell is completed by a crystallographic twofold rotation axis, and the two benzene rings of the complete mol­ecule make a dihedral angle of 60.5 (3)°. Furthermore, inter­molecular weak C—H⋯O hydrogen bonds link adjacent mol­ecules, forming a two-dimensional sheet. These sheets are stablized by face-to-face weak π–π contacts [centroid–centroid distance = 3.682 (1) Å] between the nearly parallel [dihedral angle = 0.12 (7)°] benzene rings of the neighboring mol­ecules, resulting in a three-dimensional network. International Union of Crystallography 2009-09-05 /pmc/articles/PMC2970430/ /pubmed/21577785 http://dx.doi.org/10.1107/S1600536809033790 Text en © Miao et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Miao, Shao-Bin
Deng, Dong-Sheng
Liu, Xian-Ming
Ji, Bao-Ming
2,2′-Dimeth­oxy-6,6′-dinitro­biphen­yl
title 2,2′-Dimeth­oxy-6,6′-dinitro­biphen­yl
title_full 2,2′-Dimeth­oxy-6,6′-dinitro­biphen­yl
title_fullStr 2,2′-Dimeth­oxy-6,6′-dinitro­biphen­yl
title_full_unstemmed 2,2′-Dimeth­oxy-6,6′-dinitro­biphen­yl
title_short 2,2′-Dimeth­oxy-6,6′-dinitro­biphen­yl
title_sort 2,2′-dimeth­oxy-6,6′-dinitro­biphen­yl
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2970430/
https://www.ncbi.nlm.nih.gov/pubmed/21577785
http://dx.doi.org/10.1107/S1600536809033790
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