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2,2′-Dimethoxy-6,6′-dinitrobiphenyl
In the title compound, C(14)H(12)N(2)O(6), the half molecule in the asymmetric unit of the cell is completed by a crystallographic twofold rotation axis, and the two benzene rings of the complete molecule make a dihedral angle of 60.5 (3)°. Furthermore, intermolecular weak C—H⋯O hydrogen bonds li...
Autores principales: | , , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2009
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2970430/ https://www.ncbi.nlm.nih.gov/pubmed/21577785 http://dx.doi.org/10.1107/S1600536809033790 |
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author | Miao, Shao-Bin Deng, Dong-Sheng Liu, Xian-Ming Ji, Bao-Ming |
author_facet | Miao, Shao-Bin Deng, Dong-Sheng Liu, Xian-Ming Ji, Bao-Ming |
author_sort | Miao, Shao-Bin |
collection | PubMed |
description | In the title compound, C(14)H(12)N(2)O(6), the half molecule in the asymmetric unit of the cell is completed by a crystallographic twofold rotation axis, and the two benzene rings of the complete molecule make a dihedral angle of 60.5 (3)°. Furthermore, intermolecular weak C—H⋯O hydrogen bonds link adjacent molecules, forming a two-dimensional sheet. These sheets are stablized by face-to-face weak π–π contacts [centroid–centroid distance = 3.682 (1) Å] between the nearly parallel [dihedral angle = 0.12 (7)°] benzene rings of the neighboring molecules, resulting in a three-dimensional network. |
format | Text |
id | pubmed-2970430 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2009 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29704302010-12-30 2,2′-Dimethoxy-6,6′-dinitrobiphenyl Miao, Shao-Bin Deng, Dong-Sheng Liu, Xian-Ming Ji, Bao-Ming Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(14)H(12)N(2)O(6), the half molecule in the asymmetric unit of the cell is completed by a crystallographic twofold rotation axis, and the two benzene rings of the complete molecule make a dihedral angle of 60.5 (3)°. Furthermore, intermolecular weak C—H⋯O hydrogen bonds link adjacent molecules, forming a two-dimensional sheet. These sheets are stablized by face-to-face weak π–π contacts [centroid–centroid distance = 3.682 (1) Å] between the nearly parallel [dihedral angle = 0.12 (7)°] benzene rings of the neighboring molecules, resulting in a three-dimensional network. International Union of Crystallography 2009-09-05 /pmc/articles/PMC2970430/ /pubmed/21577785 http://dx.doi.org/10.1107/S1600536809033790 Text en © Miao et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Miao, Shao-Bin Deng, Dong-Sheng Liu, Xian-Ming Ji, Bao-Ming 2,2′-Dimethoxy-6,6′-dinitrobiphenyl |
title | 2,2′-Dimethoxy-6,6′-dinitrobiphenyl |
title_full | 2,2′-Dimethoxy-6,6′-dinitrobiphenyl |
title_fullStr | 2,2′-Dimethoxy-6,6′-dinitrobiphenyl |
title_full_unstemmed | 2,2′-Dimethoxy-6,6′-dinitrobiphenyl |
title_short | 2,2′-Dimethoxy-6,6′-dinitrobiphenyl |
title_sort | 2,2′-dimethoxy-6,6′-dinitrobiphenyl |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2970430/ https://www.ncbi.nlm.nih.gov/pubmed/21577785 http://dx.doi.org/10.1107/S1600536809033790 |
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