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Bis(2-fluoro­benzoato-κ(2) O,O′)bis­(1,10-phenanthroline-κ(2) N,N′)lead(II) dihydrate

In the title compound, [Pb(C(7)H(4)FO(2))(2)(C(12)H(8)N(2))(2)]·2H(2)O, the Pb(II) atom is coordinated by four N atoms from two bidentate chelating 1,10-phenanthroline (phen) ligands and four O atoms from two 2-fluoro­benzoate ligands in an irregular polyhedral coordination geometry. Two carboxyl­at...

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Detalles Bibliográficos
Autor principal: Zhang, Bi-Song
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2970442/
https://www.ncbi.nlm.nih.gov/pubmed/21577705
http://dx.doi.org/10.1107/S1600536809035016
Descripción
Sumario:In the title compound, [Pb(C(7)H(4)FO(2))(2)(C(12)H(8)N(2))(2)]·2H(2)O, the Pb(II) atom is coordinated by four N atoms from two bidentate chelating 1,10-phenanthroline (phen) ligands and four O atoms from two 2-fluoro­benzoate ligands in an irregular polyhedral coordination geometry. Two carboxyl­ate O atoms and one F atom are each disordered over two sites with occupancy factors of 0.60 and 0.40. The dihedral angle between the two phen ligands is 89.9 (1)°. The mean inter­planar distances are alternatively of 3.44 (3) and 3.45 (3) Å, indicating π–π stacking inter­actions between the neighboring phen ligands. In the crystal, O—H⋯O, O—H⋯F and C—H⋯O hydrogen bonds link the complex mol­ecules and uncoordinated water mol­ecules into a supra­molecular network.