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Bis(2-fluorobenzoato-κ(2) O,O′)bis(1,10-phenanthroline-κ(2) N,N′)lead(II) dihydrate
In the title compound, [Pb(C(7)H(4)FO(2))(2)(C(12)H(8)N(2))(2)]·2H(2)O, the Pb(II) atom is coordinated by four N atoms from two bidentate chelating 1,10-phenanthroline (phen) ligands and four O atoms from two 2-fluorobenzoate ligands in an irregular polyhedral coordination geometry. Two carboxylat...
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2009
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2970442/ https://www.ncbi.nlm.nih.gov/pubmed/21577705 http://dx.doi.org/10.1107/S1600536809035016 |
Sumario: | In the title compound, [Pb(C(7)H(4)FO(2))(2)(C(12)H(8)N(2))(2)]·2H(2)O, the Pb(II) atom is coordinated by four N atoms from two bidentate chelating 1,10-phenanthroline (phen) ligands and four O atoms from two 2-fluorobenzoate ligands in an irregular polyhedral coordination geometry. Two carboxylate O atoms and one F atom are each disordered over two sites with occupancy factors of 0.60 and 0.40. The dihedral angle between the two phen ligands is 89.9 (1)°. The mean interplanar distances are alternatively of 3.44 (3) and 3.45 (3) Å, indicating π–π stacking interactions between the neighboring phen ligands. In the crystal, O—H⋯O, O—H⋯F and C—H⋯O hydrogen bonds link the complex molecules and uncoordinated water molecules into a supramolecular network. |
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