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Bis(2-fluoro­benzoato-κ(2) O,O′)bis­(1,10-phenanthroline-κ(2) N,N′)lead(II) dihydrate

In the title compound, [Pb(C(7)H(4)FO(2))(2)(C(12)H(8)N(2))(2)]·2H(2)O, the Pb(II) atom is coordinated by four N atoms from two bidentate chelating 1,10-phenanthroline (phen) ligands and four O atoms from two 2-fluoro­benzoate ligands in an irregular polyhedral coordination geometry. Two carboxyl­at...

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Detalles Bibliográficos
Autor principal: Zhang, Bi-Song
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2970442/
https://www.ncbi.nlm.nih.gov/pubmed/21577705
http://dx.doi.org/10.1107/S1600536809035016
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author Zhang, Bi-Song
author_facet Zhang, Bi-Song
author_sort Zhang, Bi-Song
collection PubMed
description In the title compound, [Pb(C(7)H(4)FO(2))(2)(C(12)H(8)N(2))(2)]·2H(2)O, the Pb(II) atom is coordinated by four N atoms from two bidentate chelating 1,10-phenanthroline (phen) ligands and four O atoms from two 2-fluoro­benzoate ligands in an irregular polyhedral coordination geometry. Two carboxyl­ate O atoms and one F atom are each disordered over two sites with occupancy factors of 0.60 and 0.40. The dihedral angle between the two phen ligands is 89.9 (1)°. The mean inter­planar distances are alternatively of 3.44 (3) and 3.45 (3) Å, indicating π–π stacking inter­actions between the neighboring phen ligands. In the crystal, O—H⋯O, O—H⋯F and C—H⋯O hydrogen bonds link the complex mol­ecules and uncoordinated water mol­ecules into a supra­molecular network.
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spelling pubmed-29704422010-12-30 Bis(2-fluoro­benzoato-κ(2) O,O′)bis­(1,10-phenanthroline-κ(2) N,N′)lead(II) dihydrate Zhang, Bi-Song Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Pb(C(7)H(4)FO(2))(2)(C(12)H(8)N(2))(2)]·2H(2)O, the Pb(II) atom is coordinated by four N atoms from two bidentate chelating 1,10-phenanthroline (phen) ligands and four O atoms from two 2-fluoro­benzoate ligands in an irregular polyhedral coordination geometry. Two carboxyl­ate O atoms and one F atom are each disordered over two sites with occupancy factors of 0.60 and 0.40. The dihedral angle between the two phen ligands is 89.9 (1)°. The mean inter­planar distances are alternatively of 3.44 (3) and 3.45 (3) Å, indicating π–π stacking inter­actions between the neighboring phen ligands. In the crystal, O—H⋯O, O—H⋯F and C—H⋯O hydrogen bonds link the complex mol­ecules and uncoordinated water mol­ecules into a supra­molecular network. International Union of Crystallography 2009-09-05 /pmc/articles/PMC2970442/ /pubmed/21577705 http://dx.doi.org/10.1107/S1600536809035016 Text en © Bi-Song Zhang 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Zhang, Bi-Song
Bis(2-fluoro­benzoato-κ(2) O,O′)bis­(1,10-phenanthroline-κ(2) N,N′)lead(II) dihydrate
title Bis(2-fluoro­benzoato-κ(2) O,O′)bis­(1,10-phenanthroline-κ(2) N,N′)lead(II) dihydrate
title_full Bis(2-fluoro­benzoato-κ(2) O,O′)bis­(1,10-phenanthroline-κ(2) N,N′)lead(II) dihydrate
title_fullStr Bis(2-fluoro­benzoato-κ(2) O,O′)bis­(1,10-phenanthroline-κ(2) N,N′)lead(II) dihydrate
title_full_unstemmed Bis(2-fluoro­benzoato-κ(2) O,O′)bis­(1,10-phenanthroline-κ(2) N,N′)lead(II) dihydrate
title_short Bis(2-fluoro­benzoato-κ(2) O,O′)bis­(1,10-phenanthroline-κ(2) N,N′)lead(II) dihydrate
title_sort bis(2-fluoro­benzoato-κ(2) o,o′)bis­(1,10-phenanthroline-κ(2) n,n′)lead(ii) dihydrate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2970442/
https://www.ncbi.nlm.nih.gov/pubmed/21577705
http://dx.doi.org/10.1107/S1600536809035016
work_keys_str_mv AT zhangbisong bis2fluorobenzoatok2oobis110phenanthrolinek2nnleadiidihydrate