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Bis(2-fluorobenzoato-κ(2) O,O′)bis(1,10-phenanthroline-κ(2) N,N′)lead(II) dihydrate
In the title compound, [Pb(C(7)H(4)FO(2))(2)(C(12)H(8)N(2))(2)]·2H(2)O, the Pb(II) atom is coordinated by four N atoms from two bidentate chelating 1,10-phenanthroline (phen) ligands and four O atoms from two 2-fluorobenzoate ligands in an irregular polyhedral coordination geometry. Two carboxylat...
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2009
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2970442/ https://www.ncbi.nlm.nih.gov/pubmed/21577705 http://dx.doi.org/10.1107/S1600536809035016 |
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author | Zhang, Bi-Song |
author_facet | Zhang, Bi-Song |
author_sort | Zhang, Bi-Song |
collection | PubMed |
description | In the title compound, [Pb(C(7)H(4)FO(2))(2)(C(12)H(8)N(2))(2)]·2H(2)O, the Pb(II) atom is coordinated by four N atoms from two bidentate chelating 1,10-phenanthroline (phen) ligands and four O atoms from two 2-fluorobenzoate ligands in an irregular polyhedral coordination geometry. Two carboxylate O atoms and one F atom are each disordered over two sites with occupancy factors of 0.60 and 0.40. The dihedral angle between the two phen ligands is 89.9 (1)°. The mean interplanar distances are alternatively of 3.44 (3) and 3.45 (3) Å, indicating π–π stacking interactions between the neighboring phen ligands. In the crystal, O—H⋯O, O—H⋯F and C—H⋯O hydrogen bonds link the complex molecules and uncoordinated water molecules into a supramolecular network. |
format | Text |
id | pubmed-2970442 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2009 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29704422010-12-30 Bis(2-fluorobenzoato-κ(2) O,O′)bis(1,10-phenanthroline-κ(2) N,N′)lead(II) dihydrate Zhang, Bi-Song Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Pb(C(7)H(4)FO(2))(2)(C(12)H(8)N(2))(2)]·2H(2)O, the Pb(II) atom is coordinated by four N atoms from two bidentate chelating 1,10-phenanthroline (phen) ligands and four O atoms from two 2-fluorobenzoate ligands in an irregular polyhedral coordination geometry. Two carboxylate O atoms and one F atom are each disordered over two sites with occupancy factors of 0.60 and 0.40. The dihedral angle between the two phen ligands is 89.9 (1)°. The mean interplanar distances are alternatively of 3.44 (3) and 3.45 (3) Å, indicating π–π stacking interactions between the neighboring phen ligands. In the crystal, O—H⋯O, O—H⋯F and C—H⋯O hydrogen bonds link the complex molecules and uncoordinated water molecules into a supramolecular network. International Union of Crystallography 2009-09-05 /pmc/articles/PMC2970442/ /pubmed/21577705 http://dx.doi.org/10.1107/S1600536809035016 Text en © Bi-Song Zhang 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Zhang, Bi-Song Bis(2-fluorobenzoato-κ(2) O,O′)bis(1,10-phenanthroline-κ(2) N,N′)lead(II) dihydrate |
title | Bis(2-fluorobenzoato-κ(2)
O,O′)bis(1,10-phenanthroline-κ(2)
N,N′)lead(II) dihydrate |
title_full | Bis(2-fluorobenzoato-κ(2)
O,O′)bis(1,10-phenanthroline-κ(2)
N,N′)lead(II) dihydrate |
title_fullStr | Bis(2-fluorobenzoato-κ(2)
O,O′)bis(1,10-phenanthroline-κ(2)
N,N′)lead(II) dihydrate |
title_full_unstemmed | Bis(2-fluorobenzoato-κ(2)
O,O′)bis(1,10-phenanthroline-κ(2)
N,N′)lead(II) dihydrate |
title_short | Bis(2-fluorobenzoato-κ(2)
O,O′)bis(1,10-phenanthroline-κ(2)
N,N′)lead(II) dihydrate |
title_sort | bis(2-fluorobenzoato-κ(2)
o,o′)bis(1,10-phenanthroline-κ(2)
n,n′)lead(ii) dihydrate |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2970442/ https://www.ncbi.nlm.nih.gov/pubmed/21577705 http://dx.doi.org/10.1107/S1600536809035016 |
work_keys_str_mv | AT zhangbisong bis2fluorobenzoatok2oobis110phenanthrolinek2nnleadiidihydrate |