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(2,2′-Bipyridine-κ(2) N,N′){N-[2-oxido-5-(phenyl­diazen­yl)benzyl­idene-κO]glycinato-κ(2) N,O}copper(II)

In the title compound, [Cu(C(15)H(11)N(3)O(3))(C(10)H(8)N(2))], the Cu(II) atom is five-coordinated in a distorted square-pyramidal CuN(3)O(2) geometry. The basal positions are occupied by three donor atoms from the tridentate Schiff base ligand and by one N atom from the 2,2′-bipyridine ligand. The...

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Autores principales: Zhang, Qiu-Xia, Zhao, Gan-Qing, Zhu, Jian-Qi, Xue, Ling-Wei, Han, Yong-Jun
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2970450/
https://www.ncbi.nlm.nih.gov/pubmed/21577738
http://dx.doi.org/10.1107/S1600536809036423
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author Zhang, Qiu-Xia
Zhao, Gan-Qing
Zhu, Jian-Qi
Xue, Ling-Wei
Han, Yong-Jun
author_facet Zhang, Qiu-Xia
Zhao, Gan-Qing
Zhu, Jian-Qi
Xue, Ling-Wei
Han, Yong-Jun
author_sort Zhang, Qiu-Xia
collection PubMed
description In the title compound, [Cu(C(15)H(11)N(3)O(3))(C(10)H(8)N(2))], the Cu(II) atom is five-coordinated in a distorted square-pyramidal CuN(3)O(2) geometry. The basal positions are occupied by three donor atoms from the tridentate Schiff base ligand and by one N atom from the 2,2′-bipyridine ligand. The axial position is occupied by the other N atom of the 2,2′-bipyridine ligand. The crystal structure is consolidated by weak C—H⋯O hydrogen bonds. In addition, π–π inter­actions between adjacent pyridine rings (centroid–centroid distances = 3.238 and 3.313 Å) may also stabilize the crystal packing.
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spelling pubmed-29704502010-12-30 (2,2′-Bipyridine-κ(2) N,N′){N-[2-oxido-5-(phenyl­diazen­yl)benzyl­idene-κO]glycinato-κ(2) N,O}copper(II) Zhang, Qiu-Xia Zhao, Gan-Qing Zhu, Jian-Qi Xue, Ling-Wei Han, Yong-Jun Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Cu(C(15)H(11)N(3)O(3))(C(10)H(8)N(2))], the Cu(II) atom is five-coordinated in a distorted square-pyramidal CuN(3)O(2) geometry. The basal positions are occupied by three donor atoms from the tridentate Schiff base ligand and by one N atom from the 2,2′-bipyridine ligand. The axial position is occupied by the other N atom of the 2,2′-bipyridine ligand. The crystal structure is consolidated by weak C—H⋯O hydrogen bonds. In addition, π–π inter­actions between adjacent pyridine rings (centroid–centroid distances = 3.238 and 3.313 Å) may also stabilize the crystal packing. International Union of Crystallography 2009-09-16 /pmc/articles/PMC2970450/ /pubmed/21577738 http://dx.doi.org/10.1107/S1600536809036423 Text en © Zhang et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Zhang, Qiu-Xia
Zhao, Gan-Qing
Zhu, Jian-Qi
Xue, Ling-Wei
Han, Yong-Jun
(2,2′-Bipyridine-κ(2) N,N′){N-[2-oxido-5-(phenyl­diazen­yl)benzyl­idene-κO]glycinato-κ(2) N,O}copper(II)
title (2,2′-Bipyridine-κ(2) N,N′){N-[2-oxido-5-(phenyl­diazen­yl)benzyl­idene-κO]glycinato-κ(2) N,O}copper(II)
title_full (2,2′-Bipyridine-κ(2) N,N′){N-[2-oxido-5-(phenyl­diazen­yl)benzyl­idene-κO]glycinato-κ(2) N,O}copper(II)
title_fullStr (2,2′-Bipyridine-κ(2) N,N′){N-[2-oxido-5-(phenyl­diazen­yl)benzyl­idene-κO]glycinato-κ(2) N,O}copper(II)
title_full_unstemmed (2,2′-Bipyridine-κ(2) N,N′){N-[2-oxido-5-(phenyl­diazen­yl)benzyl­idene-κO]glycinato-κ(2) N,O}copper(II)
title_short (2,2′-Bipyridine-κ(2) N,N′){N-[2-oxido-5-(phenyl­diazen­yl)benzyl­idene-κO]glycinato-κ(2) N,O}copper(II)
title_sort (2,2′-bipyridine-κ(2) n,n′){n-[2-oxido-5-(phenyl­diazen­yl)benzyl­idene-κo]glycinato-κ(2) n,o}copper(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2970450/
https://www.ncbi.nlm.nih.gov/pubmed/21577738
http://dx.doi.org/10.1107/S1600536809036423
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