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(2,2′-Bipyridine-κ(2) N,N′){N-[2-oxido-5-(phenyldiazenyl)benzylidene-κO]glycinato-κ(2) N,O}copper(II)
In the title compound, [Cu(C(15)H(11)N(3)O(3))(C(10)H(8)N(2))], the Cu(II) atom is five-coordinated in a distorted square-pyramidal CuN(3)O(2) geometry. The basal positions are occupied by three donor atoms from the tridentate Schiff base ligand and by one N atom from the 2,2′-bipyridine ligand. The...
Autores principales: | , , , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2009
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2970450/ https://www.ncbi.nlm.nih.gov/pubmed/21577738 http://dx.doi.org/10.1107/S1600536809036423 |
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author | Zhang, Qiu-Xia Zhao, Gan-Qing Zhu, Jian-Qi Xue, Ling-Wei Han, Yong-Jun |
author_facet | Zhang, Qiu-Xia Zhao, Gan-Qing Zhu, Jian-Qi Xue, Ling-Wei Han, Yong-Jun |
author_sort | Zhang, Qiu-Xia |
collection | PubMed |
description | In the title compound, [Cu(C(15)H(11)N(3)O(3))(C(10)H(8)N(2))], the Cu(II) atom is five-coordinated in a distorted square-pyramidal CuN(3)O(2) geometry. The basal positions are occupied by three donor atoms from the tridentate Schiff base ligand and by one N atom from the 2,2′-bipyridine ligand. The axial position is occupied by the other N atom of the 2,2′-bipyridine ligand. The crystal structure is consolidated by weak C—H⋯O hydrogen bonds. In addition, π–π interactions between adjacent pyridine rings (centroid–centroid distances = 3.238 and 3.313 Å) may also stabilize the crystal packing. |
format | Text |
id | pubmed-2970450 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2009 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29704502010-12-30 (2,2′-Bipyridine-κ(2) N,N′){N-[2-oxido-5-(phenyldiazenyl)benzylidene-κO]glycinato-κ(2) N,O}copper(II) Zhang, Qiu-Xia Zhao, Gan-Qing Zhu, Jian-Qi Xue, Ling-Wei Han, Yong-Jun Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Cu(C(15)H(11)N(3)O(3))(C(10)H(8)N(2))], the Cu(II) atom is five-coordinated in a distorted square-pyramidal CuN(3)O(2) geometry. The basal positions are occupied by three donor atoms from the tridentate Schiff base ligand and by one N atom from the 2,2′-bipyridine ligand. The axial position is occupied by the other N atom of the 2,2′-bipyridine ligand. The crystal structure is consolidated by weak C—H⋯O hydrogen bonds. In addition, π–π interactions between adjacent pyridine rings (centroid–centroid distances = 3.238 and 3.313 Å) may also stabilize the crystal packing. International Union of Crystallography 2009-09-16 /pmc/articles/PMC2970450/ /pubmed/21577738 http://dx.doi.org/10.1107/S1600536809036423 Text en © Zhang et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Zhang, Qiu-Xia Zhao, Gan-Qing Zhu, Jian-Qi Xue, Ling-Wei Han, Yong-Jun (2,2′-Bipyridine-κ(2) N,N′){N-[2-oxido-5-(phenyldiazenyl)benzylidene-κO]glycinato-κ(2) N,O}copper(II) |
title | (2,2′-Bipyridine-κ(2)
N,N′){N-[2-oxido-5-(phenyldiazenyl)benzylidene-κO]glycinato-κ(2)
N,O}copper(II) |
title_full | (2,2′-Bipyridine-κ(2)
N,N′){N-[2-oxido-5-(phenyldiazenyl)benzylidene-κO]glycinato-κ(2)
N,O}copper(II) |
title_fullStr | (2,2′-Bipyridine-κ(2)
N,N′){N-[2-oxido-5-(phenyldiazenyl)benzylidene-κO]glycinato-κ(2)
N,O}copper(II) |
title_full_unstemmed | (2,2′-Bipyridine-κ(2)
N,N′){N-[2-oxido-5-(phenyldiazenyl)benzylidene-κO]glycinato-κ(2)
N,O}copper(II) |
title_short | (2,2′-Bipyridine-κ(2)
N,N′){N-[2-oxido-5-(phenyldiazenyl)benzylidene-κO]glycinato-κ(2)
N,O}copper(II) |
title_sort | (2,2′-bipyridine-κ(2)
n,n′){n-[2-oxido-5-(phenyldiazenyl)benzylidene-κo]glycinato-κ(2)
n,o}copper(ii) |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2970450/ https://www.ncbi.nlm.nih.gov/pubmed/21577738 http://dx.doi.org/10.1107/S1600536809036423 |
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