Bis(1,3-dibutylthiourea)dicyanido­mercury(II)

In the title compound, [Hg(CN)(2)(C(9)H(20)N(2)S)(2)], the Hg atom lies on a twofold rotation axis. There is only half a mol­ecule in the asymmetric unit. The Hg atom has a distorted tetra­hedral coordination involving the S atoms of two 1-butyl-3-propyl­thio­urea groups and the C atoms of the two C...

Descripción completa

Detalles Bibliográficos
Autores principales: Ahmad, Saeed, Sadaf, Haseeba, Akkurt, Mehmet, Sharif, Shahzad, Khan, Islam Ullah
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2970451/
https://www.ncbi.nlm.nih.gov/pubmed/21577723
http://dx.doi.org/10.1107/S1600536809035594
Descripción
Sumario:In the title compound, [Hg(CN)(2)(C(9)H(20)N(2)S)(2)], the Hg atom lies on a twofold rotation axis. There is only half a mol­ecule in the asymmetric unit. The Hg atom has a distorted tetra­hedral coordination involving the S atoms of two 1-butyl-3-propyl­thio­urea groups and the C atoms of the two CN(−) anions. In the crystal packing, adjacent mol­ecules are connected by inter­molecular N—H⋯N and N—H⋯S hydrogen bonds, forming infinite chains in three dimensions.

Ejemplares similares