Bis(1,3-dibutylthiourea)dicyanido­mercury(II)

In the title compound, [Hg(CN)(2)(C(9)H(20)N(2)S)(2)], the Hg atom lies on a twofold rotation axis. There is only half a mol­ecule in the asymmetric unit. The Hg atom has a distorted tetra­hedral coordination involving the S atoms of two 1-butyl-3-propyl­thio­urea groups and the C atoms of the two C...

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Autores principales: Ahmad, Saeed, Sadaf, Haseeba, Akkurt, Mehmet, Sharif, Shahzad, Khan, Islam Ullah
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2970451/
https://www.ncbi.nlm.nih.gov/pubmed/21577723
http://dx.doi.org/10.1107/S1600536809035594
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author Ahmad, Saeed
Sadaf, Haseeba
Akkurt, Mehmet
Sharif, Shahzad
Khan, Islam Ullah
author_facet Ahmad, Saeed
Sadaf, Haseeba
Akkurt, Mehmet
Sharif, Shahzad
Khan, Islam Ullah
author_sort Ahmad, Saeed
collection PubMed
description In the title compound, [Hg(CN)(2)(C(9)H(20)N(2)S)(2)], the Hg atom lies on a twofold rotation axis. There is only half a mol­ecule in the asymmetric unit. The Hg atom has a distorted tetra­hedral coordination involving the S atoms of two 1-butyl-3-propyl­thio­urea groups and the C atoms of the two CN(−) anions. In the crystal packing, adjacent mol­ecules are connected by inter­molecular N—H⋯N and N—H⋯S hydrogen bonds, forming infinite chains in three dimensions.
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spelling pubmed-29704512010-12-30 Bis(1,3-dibutylthiourea)dicyanido­mercury(II) Ahmad, Saeed Sadaf, Haseeba Akkurt, Mehmet Sharif, Shahzad Khan, Islam Ullah Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Hg(CN)(2)(C(9)H(20)N(2)S)(2)], the Hg atom lies on a twofold rotation axis. There is only half a mol­ecule in the asymmetric unit. The Hg atom has a distorted tetra­hedral coordination involving the S atoms of two 1-butyl-3-propyl­thio­urea groups and the C atoms of the two CN(−) anions. In the crystal packing, adjacent mol­ecules are connected by inter­molecular N—H⋯N and N—H⋯S hydrogen bonds, forming infinite chains in three dimensions. International Union of Crystallography 2009-09-09 /pmc/articles/PMC2970451/ /pubmed/21577723 http://dx.doi.org/10.1107/S1600536809035594 Text en © Ahmad et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Ahmad, Saeed
Sadaf, Haseeba
Akkurt, Mehmet
Sharif, Shahzad
Khan, Islam Ullah
Bis(1,3-dibutylthiourea)dicyanido­mercury(II)
title Bis(1,3-dibutylthiourea)dicyanido­mercury(II)
title_full Bis(1,3-dibutylthiourea)dicyanido­mercury(II)
title_fullStr Bis(1,3-dibutylthiourea)dicyanido­mercury(II)
title_full_unstemmed Bis(1,3-dibutylthiourea)dicyanido­mercury(II)
title_short Bis(1,3-dibutylthiourea)dicyanido­mercury(II)
title_sort bis(1,3-dibutylthiourea)dicyanido­mercury(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2970451/
https://www.ncbi.nlm.nih.gov/pubmed/21577723
http://dx.doi.org/10.1107/S1600536809035594
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