N (1),N (2)-Bis­(2,6-di­methyl­phen­yl)-N (1)-hydroxyformamidine N,N′-bis­(2,6-dimethyl­phen­yl)-N-oxidoformamidinium dichloro­methane solvate

The title compound, 2C(17)H(20)N(2)O·CH(2)Cl(2), was obtained by N-oxidation of the parent formamidine with m-chloro-peroxy­benzoic acid (m-CPBA). This is the first use of the above-mentioned synthetic route for the preparation of hydroxy­amidines. The title compound crystallizes as a cyclic dimer r...

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Detalles Bibliográficos
Autores principales: Cibian, Mihaela, Derossi, Sofia, Hanan, Garry S.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2970452/
https://www.ncbi.nlm.nih.gov/pubmed/21577936
http://dx.doi.org/10.1107/S1600536809036708
Descripción
Sumario:The title compound, 2C(17)H(20)N(2)O·CH(2)Cl(2), was obtained by N-oxidation of the parent formamidine with m-chloro-peroxy­benzoic acid (m-CPBA). This is the first use of the above-mentioned synthetic route for the preparation of hydroxy­amidines. The title compound crystallizes as a cyclic dimer resulting from the presence of O—H⋯O and N—H⋯N hydrogen bonds.

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