N (1),N (2)-Bis­(2,6-di­methyl­phen­yl)-N (1)-hydroxyformamidine N,N′-bis­(2,6-dimethyl­phen­yl)-N-oxidoformamidinium dichloro­methane solvate

The title compound, 2C(17)H(20)N(2)O·CH(2)Cl(2), was obtained by N-oxidation of the parent formamidine with m-chloro-peroxy­benzoic acid (m-CPBA). This is the first use of the above-mentioned synthetic route for the preparation of hydroxy­amidines. The title compound crystallizes as a cyclic dimer r...

Descripción completa

Detalles Bibliográficos
Autores principales: Cibian, Mihaela, Derossi, Sofia, Hanan, Garry S.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2970452/
https://www.ncbi.nlm.nih.gov/pubmed/21577936
http://dx.doi.org/10.1107/S1600536809036708
_version_ 1782190447351824384
author Cibian, Mihaela
Derossi, Sofia
Hanan, Garry S.
author_facet Cibian, Mihaela
Derossi, Sofia
Hanan, Garry S.
author_sort Cibian, Mihaela
collection PubMed
description The title compound, 2C(17)H(20)N(2)O·CH(2)Cl(2), was obtained by N-oxidation of the parent formamidine with m-chloro-peroxy­benzoic acid (m-CPBA). This is the first use of the above-mentioned synthetic route for the preparation of hydroxy­amidines. The title compound crystallizes as a cyclic dimer resulting from the presence of O—H⋯O and N—H⋯N hydrogen bonds.
format Text
id pubmed-2970452
institution National Center for Biotechnology Information
language English
publishDate 2009
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-29704522010-12-30 N (1),N (2)-Bis­(2,6-di­methyl­phen­yl)-N (1)-hydroxyformamidine N,N′-bis­(2,6-dimethyl­phen­yl)-N-oxidoformamidinium dichloro­methane solvate Cibian, Mihaela Derossi, Sofia Hanan, Garry S. Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, 2C(17)H(20)N(2)O·CH(2)Cl(2), was obtained by N-oxidation of the parent formamidine with m-chloro-peroxy­benzoic acid (m-CPBA). This is the first use of the above-mentioned synthetic route for the preparation of hydroxy­amidines. The title compound crystallizes as a cyclic dimer resulting from the presence of O—H⋯O and N—H⋯N hydrogen bonds. International Union of Crystallography 2009-09-19 /pmc/articles/PMC2970452/ /pubmed/21577936 http://dx.doi.org/10.1107/S1600536809036708 Text en © Cibian et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Cibian, Mihaela
Derossi, Sofia
Hanan, Garry S.
N (1),N (2)-Bis­(2,6-di­methyl­phen­yl)-N (1)-hydroxyformamidine N,N′-bis­(2,6-dimethyl­phen­yl)-N-oxidoformamidinium dichloro­methane solvate
title N (1),N (2)-Bis­(2,6-di­methyl­phen­yl)-N (1)-hydroxyformamidine N,N′-bis­(2,6-dimethyl­phen­yl)-N-oxidoformamidinium dichloro­methane solvate
title_full N (1),N (2)-Bis­(2,6-di­methyl­phen­yl)-N (1)-hydroxyformamidine N,N′-bis­(2,6-dimethyl­phen­yl)-N-oxidoformamidinium dichloro­methane solvate
title_fullStr N (1),N (2)-Bis­(2,6-di­methyl­phen­yl)-N (1)-hydroxyformamidine N,N′-bis­(2,6-dimethyl­phen­yl)-N-oxidoformamidinium dichloro­methane solvate
title_full_unstemmed N (1),N (2)-Bis­(2,6-di­methyl­phen­yl)-N (1)-hydroxyformamidine N,N′-bis­(2,6-dimethyl­phen­yl)-N-oxidoformamidinium dichloro­methane solvate
title_short N (1),N (2)-Bis­(2,6-di­methyl­phen­yl)-N (1)-hydroxyformamidine N,N′-bis­(2,6-dimethyl­phen­yl)-N-oxidoformamidinium dichloro­methane solvate
title_sort n (1),n (2)-bis­(2,6-di­methyl­phen­yl)-n (1)-hydroxyformamidine n,n′-bis­(2,6-dimethyl­phen­yl)-n-oxidoformamidinium dichloro­methane solvate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2970452/
https://www.ncbi.nlm.nih.gov/pubmed/21577936
http://dx.doi.org/10.1107/S1600536809036708
work_keys_str_mv AT cibianmihaela n1n2bis26dimethylphenyln1hydroxyformamidinennbis26dimethylphenylnoxidoformamidiniumdichloromethanesolvate
AT derossisofia n1n2bis26dimethylphenyln1hydroxyformamidinennbis26dimethylphenylnoxidoformamidiniumdichloromethanesolvate
AT hanangarrys n1n2bis26dimethylphenyln1hydroxyformamidinennbis26dimethylphenylnoxidoformamidiniumdichloromethanesolvate

Ejemplares similares