syn,syn-15,17-Di-2-naphthyl­hexa­cyclo­[10.2.1.1(3,10).1(5,8).0(2,11).0(4,9)]hepta­decane deuterochloro­form monosolvate

The main molecule of the title compound, C(37)H(36)·CDCl(3), is a hydro­carbon with two naphthalene segments attached to opposite ends of a rigid norbornylogous spacer with an overall structure that is approximately C-shaped. The dihedral angle between the naphthalene ring planes is 9.27 (7)°. The c...

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Detalles Bibliográficos
Autores principales: DeBlase, Andrew F., Thong, Darence Ca, Nadeau, Jocelyn M., Gebhart, David, Provo, Jonathan, Foxman, Bruce M.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2970454/
https://www.ncbi.nlm.nih.gov/pubmed/21577884
http://dx.doi.org/10.1107/S160053680903565X
Descripción
Sumario:The main molecule of the title compound, C(37)H(36)·CDCl(3), is a hydro­carbon with two naphthalene segments attached to opposite ends of a rigid norbornylogous spacer with an overall structure that is approximately C-shaped. The dihedral angle between the naphthalene ring planes is 9.27 (7)°. The cleft that exists between the naphthalene rings is large enough that the compound crystallizes with a solvent mol­ecule (CDCl(3)) in the cleft. The CDCl(3) solvent mol­ecule is present in two disordered orientations in a 3:2 ratio, each involving C—D⋯π to C (6) ring centers.

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