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syn,syn-15,17-Di-2-naphthylhexacyclo[10.2.1.1(3,10).1(5,8).0(2,11).0(4,9)]heptadecane deuterochloroform monosolvate
The main molecule of the title compound, C(37)H(36)·CDCl(3), is a hydrocarbon with two naphthalene segments attached to opposite ends of a rigid norbornylogous spacer with an overall structure that is approximately C-shaped. The dihedral angle between the naphthalene ring planes is 9.27 (7)°. The c...
| Autores principales: | , , , , , |
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| Formato: | Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2009
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2970454/ https://www.ncbi.nlm.nih.gov/pubmed/21577884 http://dx.doi.org/10.1107/S160053680903565X |
| _version_ | 1782190447974678528 |
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| author | DeBlase, Andrew F. Thong, Darence Ca Nadeau, Jocelyn M. Gebhart, David Provo, Jonathan Foxman, Bruce M. |
| author_facet | DeBlase, Andrew F. Thong, Darence Ca Nadeau, Jocelyn M. Gebhart, David Provo, Jonathan Foxman, Bruce M. |
| author_sort | DeBlase, Andrew F. |
| collection | PubMed |
| description | The main molecule of the title compound, C(37)H(36)·CDCl(3), is a hydrocarbon with two naphthalene segments attached to opposite ends of a rigid norbornylogous spacer with an overall structure that is approximately C-shaped. The dihedral angle between the naphthalene ring planes is 9.27 (7)°. The cleft that exists between the naphthalene rings is large enough that the compound crystallizes with a solvent molecule (CDCl(3)) in the cleft. The CDCl(3) solvent molecule is present in two disordered orientations in a 3:2 ratio, each involving C—D⋯π to C (6) ring centers. |
| format | Text |
| id | pubmed-2970454 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2009 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-29704542010-12-30 syn,syn-15,17-Di-2-naphthylhexacyclo[10.2.1.1(3,10).1(5,8).0(2,11).0(4,9)]heptadecane deuterochloroform monosolvate DeBlase, Andrew F. Thong, Darence Ca Nadeau, Jocelyn M. Gebhart, David Provo, Jonathan Foxman, Bruce M. Acta Crystallogr Sect E Struct Rep Online Organic Papers The main molecule of the title compound, C(37)H(36)·CDCl(3), is a hydrocarbon with two naphthalene segments attached to opposite ends of a rigid norbornylogous spacer with an overall structure that is approximately C-shaped. The dihedral angle between the naphthalene ring planes is 9.27 (7)°. The cleft that exists between the naphthalene rings is large enough that the compound crystallizes with a solvent molecule (CDCl(3)) in the cleft. The CDCl(3) solvent molecule is present in two disordered orientations in a 3:2 ratio, each involving C—D⋯π to C (6) ring centers. International Union of Crystallography 2009-09-12 /pmc/articles/PMC2970454/ /pubmed/21577884 http://dx.doi.org/10.1107/S160053680903565X Text en © DeBlase et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Organic Papers DeBlase, Andrew F. Thong, Darence Ca Nadeau, Jocelyn M. Gebhart, David Provo, Jonathan Foxman, Bruce M. syn,syn-15,17-Di-2-naphthylhexacyclo[10.2.1.1(3,10).1(5,8).0(2,11).0(4,9)]heptadecane deuterochloroform monosolvate |
| title |
syn,syn-15,17-Di-2-naphthylhexacyclo[10.2.1.1(3,10).1(5,8).0(2,11).0(4,9)]heptadecane deuterochloroform monosolvate |
| title_full |
syn,syn-15,17-Di-2-naphthylhexacyclo[10.2.1.1(3,10).1(5,8).0(2,11).0(4,9)]heptadecane deuterochloroform monosolvate |
| title_fullStr |
syn,syn-15,17-Di-2-naphthylhexacyclo[10.2.1.1(3,10).1(5,8).0(2,11).0(4,9)]heptadecane deuterochloroform monosolvate |
| title_full_unstemmed |
syn,syn-15,17-Di-2-naphthylhexacyclo[10.2.1.1(3,10).1(5,8).0(2,11).0(4,9)]heptadecane deuterochloroform monosolvate |
| title_short |
syn,syn-15,17-Di-2-naphthylhexacyclo[10.2.1.1(3,10).1(5,8).0(2,11).0(4,9)]heptadecane deuterochloroform monosolvate |
| title_sort | syn,syn-15,17-di-2-naphthylhexacyclo[10.2.1.1(3,10).1(5,8).0(2,11).0(4,9)]heptadecane deuterochloroform monosolvate |
| topic | Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2970454/ https://www.ncbi.nlm.nih.gov/pubmed/21577884 http://dx.doi.org/10.1107/S160053680903565X |
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