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Dichlorido(2,9-dipropoxy-1,10-phenanthroline-κ(2) N,N′)cadmium(II)
In the title complex, [CdCl(2)(C(18)H(20)N(2)O(2))], the Cd(II) ion is coordinated by two N atoms from a bis-chelating 2,9-dipropoxy-1,10-phenanthroline ligand and two Cl atoms in a distorted tetrahedral environment. The two Cd—Cl bond distances are significantly different from each other and the...
| Autores principales: | , , |
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| Formato: | Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2009
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2970460/ https://www.ncbi.nlm.nih.gov/pubmed/21577762 http://dx.doi.org/10.1107/S1600536809038124 |
| Sumario: | In the title complex, [CdCl(2)(C(18)H(20)N(2)O(2))], the Cd(II) ion is coordinated by two N atoms from a bis-chelating 2,9-dipropoxy-1,10-phenanthroline ligand and two Cl atoms in a distorted tetrahedral environment. The two Cd—Cl bond distances are significantly different from each other and the N—Cd—N bond angle is acute. In the crystal structure, there are π–π stacking interactions between symmetry-related phenanthroline ring systems, with a centroid–centroid distance of 3.585 (3) Å. |
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