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Dichlorido(2,9-dipropoxy-1,10-phenanthroline-κ(2) N,N′)cadmium(II)
In the title complex, [CdCl(2)(C(18)H(20)N(2)O(2))], the Cd(II) ion is coordinated by two N atoms from a bis-chelating 2,9-dipropoxy-1,10-phenanthroline ligand and two Cl atoms in a distorted tetrahedral environment. The two Cd—Cl bond distances are significantly different from each other and the...
| Autores principales: | , , |
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| Formato: | Texto |
| Lenguaje: | English |
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International Union of Crystallography
2009
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2970460/ https://www.ncbi.nlm.nih.gov/pubmed/21577762 http://dx.doi.org/10.1107/S1600536809038124 |
| _version_ | 1782190449811783680 |
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| author | Niu, Cao-Yuan Zheng, Xian-Fu Dang, Yu-Li |
| author_facet | Niu, Cao-Yuan Zheng, Xian-Fu Dang, Yu-Li |
| author_sort | Niu, Cao-Yuan |
| collection | PubMed |
| description | In the title complex, [CdCl(2)(C(18)H(20)N(2)O(2))], the Cd(II) ion is coordinated by two N atoms from a bis-chelating 2,9-dipropoxy-1,10-phenanthroline ligand and two Cl atoms in a distorted tetrahedral environment. The two Cd—Cl bond distances are significantly different from each other and the N—Cd—N bond angle is acute. In the crystal structure, there are π–π stacking interactions between symmetry-related phenanthroline ring systems, with a centroid–centroid distance of 3.585 (3) Å. |
| format | Text |
| id | pubmed-2970460 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2009 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-29704602010-12-30 Dichlorido(2,9-dipropoxy-1,10-phenanthroline-κ(2) N,N′)cadmium(II) Niu, Cao-Yuan Zheng, Xian-Fu Dang, Yu-Li Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title complex, [CdCl(2)(C(18)H(20)N(2)O(2))], the Cd(II) ion is coordinated by two N atoms from a bis-chelating 2,9-dipropoxy-1,10-phenanthroline ligand and two Cl atoms in a distorted tetrahedral environment. The two Cd—Cl bond distances are significantly different from each other and the N—Cd—N bond angle is acute. In the crystal structure, there are π–π stacking interactions between symmetry-related phenanthroline ring systems, with a centroid–centroid distance of 3.585 (3) Å. International Union of Crystallography 2009-09-26 /pmc/articles/PMC2970460/ /pubmed/21577762 http://dx.doi.org/10.1107/S1600536809038124 Text en © Niu et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Niu, Cao-Yuan Zheng, Xian-Fu Dang, Yu-Li Dichlorido(2,9-dipropoxy-1,10-phenanthroline-κ(2) N,N′)cadmium(II) |
| title | Dichlorido(2,9-dipropoxy-1,10-phenanthroline-κ(2)
N,N′)cadmium(II) |
| title_full | Dichlorido(2,9-dipropoxy-1,10-phenanthroline-κ(2)
N,N′)cadmium(II) |
| title_fullStr | Dichlorido(2,9-dipropoxy-1,10-phenanthroline-κ(2)
N,N′)cadmium(II) |
| title_full_unstemmed | Dichlorido(2,9-dipropoxy-1,10-phenanthroline-κ(2)
N,N′)cadmium(II) |
| title_short | Dichlorido(2,9-dipropoxy-1,10-phenanthroline-κ(2)
N,N′)cadmium(II) |
| title_sort | dichlorido(2,9-dipropoxy-1,10-phenanthroline-κ(2)
n,n′)cadmium(ii) |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2970460/ https://www.ncbi.nlm.nih.gov/pubmed/21577762 http://dx.doi.org/10.1107/S1600536809038124 |
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