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catena-Poly[[[aqua(2,2′-bipyridine)manganese(II)]-μ-5-methoxyisophthalato-κ(3) O,O′:O′′] monohydrate]
In the title compound, {[Mn(C(8)H(4)O(4))(C(10)H(8)N(2))(H(2)O)]·H(2)O}(n), the Mn(II) centre is octahedrally coordinated by three O atoms from two 5-methoxyisophthalate (CH(3)O-ip) ligands, a fourth from a coordinated water molecule and two N atoms from one chelating 2,2′-bipyridine (2,2-bipy) l...
Autor principal: | |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2009
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2970467/ https://www.ncbi.nlm.nih.gov/pubmed/21577709 http://dx.doi.org/10.1107/S1600536809035466 |
Sumario: | In the title compound, {[Mn(C(8)H(4)O(4))(C(10)H(8)N(2))(H(2)O)]·H(2)O}(n), the Mn(II) centre is octahedrally coordinated by three O atoms from two 5-methoxyisophthalate (CH(3)O-ip) ligands, a fourth from a coordinated water molecule and two N atoms from one chelating 2,2′-bipyridine (2,2-bipy) ligand. Each pair of adjacent Mn(II) atoms is bridged by a CH(3)O-ip ligand, forming a helical chain running along a crystallographic 2(1) axis in the c-axis direction. These chains are decorated with 2,2′-bipy ligands on alternating sides. O—H⋯O hydrogen bonding involving the water molecules stabilizes the crystal structure. |
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