Cargando…

catena-Poly[[[aqua­(2,2′-bipyridine)manganese(II)]-μ-5-methoxy­iso­phthalato-κ(3) O,O′:O′′] monohydrate]

In the title compound, {[Mn(C(8)H(4)O(4))(C(10)H(8)N(2))(H(2)O)]·H(2)O}(n), the Mn(II) centre is octa­hedrally coordinated by three O atoms from two 5-methoxy­isophthalate (CH(3)O-ip) ligands, a fourth from a coordinated water mol­ecule and two N atoms from one chelating 2,2′-bipyridine (2,2-bipy) l...

Descripción completa

Detalles Bibliográficos
Autor principal: Shen, Su-Mei
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2970467/
https://www.ncbi.nlm.nih.gov/pubmed/21577709
http://dx.doi.org/10.1107/S1600536809035466
_version_ 1782190451437076480
author Shen, Su-Mei
author_facet Shen, Su-Mei
author_sort Shen, Su-Mei
collection PubMed
description In the title compound, {[Mn(C(8)H(4)O(4))(C(10)H(8)N(2))(H(2)O)]·H(2)O}(n), the Mn(II) centre is octa­hedrally coordinated by three O atoms from two 5-methoxy­isophthalate (CH(3)O-ip) ligands, a fourth from a coordinated water mol­ecule and two N atoms from one chelating 2,2′-bipyridine (2,2-bipy) ligand. Each pair of adjacent Mn(II) atoms is bridged by a CH(3)O-ip ligand, forming a helical chain running along a crystallographic 2(1) axis in the c-axis direction. These chains are decorated with 2,2′-bipy ligands on alternating sides. O—H⋯O hydrogen bonding involving the water molecules stabilizes the crystal structure.
format Text
id pubmed-2970467
institution National Center for Biotechnology Information
language English
publishDate 2009
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-29704672010-12-30 catena-Poly[[[aqua­(2,2′-bipyridine)manganese(II)]-μ-5-methoxy­iso­phthalato-κ(3) O,O′:O′′] monohydrate] Shen, Su-Mei Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, {[Mn(C(8)H(4)O(4))(C(10)H(8)N(2))(H(2)O)]·H(2)O}(n), the Mn(II) centre is octa­hedrally coordinated by three O atoms from two 5-methoxy­isophthalate (CH(3)O-ip) ligands, a fourth from a coordinated water mol­ecule and two N atoms from one chelating 2,2′-bipyridine (2,2-bipy) ligand. Each pair of adjacent Mn(II) atoms is bridged by a CH(3)O-ip ligand, forming a helical chain running along a crystallographic 2(1) axis in the c-axis direction. These chains are decorated with 2,2′-bipy ligands on alternating sides. O—H⋯O hydrogen bonding involving the water molecules stabilizes the crystal structure. International Union of Crystallography 2009-09-05 /pmc/articles/PMC2970467/ /pubmed/21577709 http://dx.doi.org/10.1107/S1600536809035466 Text en © Su-Mei Shen 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Shen, Su-Mei
catena-Poly[[[aqua­(2,2′-bipyridine)manganese(II)]-μ-5-methoxy­iso­phthalato-κ(3) O,O′:O′′] monohydrate]
title catena-Poly[[[aqua­(2,2′-bipyridine)manganese(II)]-μ-5-methoxy­iso­phthalato-κ(3) O,O′:O′′] monohydrate]
title_full catena-Poly[[[aqua­(2,2′-bipyridine)manganese(II)]-μ-5-methoxy­iso­phthalato-κ(3) O,O′:O′′] monohydrate]
title_fullStr catena-Poly[[[aqua­(2,2′-bipyridine)manganese(II)]-μ-5-methoxy­iso­phthalato-κ(3) O,O′:O′′] monohydrate]
title_full_unstemmed catena-Poly[[[aqua­(2,2′-bipyridine)manganese(II)]-μ-5-methoxy­iso­phthalato-κ(3) O,O′:O′′] monohydrate]
title_short catena-Poly[[[aqua­(2,2′-bipyridine)manganese(II)]-μ-5-methoxy­iso­phthalato-κ(3) O,O′:O′′] monohydrate]
title_sort catena-poly[[[aqua­(2,2′-bipyridine)manganese(ii)]-μ-5-methoxy­iso­phthalato-κ(3) o,o′:o′′] monohydrate]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2970467/
https://www.ncbi.nlm.nih.gov/pubmed/21577709
http://dx.doi.org/10.1107/S1600536809035466
work_keys_str_mv AT shensumei catenapolyaqua22bipyridinemanganeseiim5methoxyisophthalatok3ooomonohydrate