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catena-Poly[[[aqua(2,2′-bipyridine)manganese(II)]-μ-5-methoxyisophthalato-κ(3) O,O′:O′′] monohydrate]
In the title compound, {[Mn(C(8)H(4)O(4))(C(10)H(8)N(2))(H(2)O)]·H(2)O}(n), the Mn(II) centre is octahedrally coordinated by three O atoms from two 5-methoxyisophthalate (CH(3)O-ip) ligands, a fourth from a coordinated water molecule and two N atoms from one chelating 2,2′-bipyridine (2,2-bipy) l...
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2009
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2970467/ https://www.ncbi.nlm.nih.gov/pubmed/21577709 http://dx.doi.org/10.1107/S1600536809035466 |
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author | Shen, Su-Mei |
author_facet | Shen, Su-Mei |
author_sort | Shen, Su-Mei |
collection | PubMed |
description | In the title compound, {[Mn(C(8)H(4)O(4))(C(10)H(8)N(2))(H(2)O)]·H(2)O}(n), the Mn(II) centre is octahedrally coordinated by three O atoms from two 5-methoxyisophthalate (CH(3)O-ip) ligands, a fourth from a coordinated water molecule and two N atoms from one chelating 2,2′-bipyridine (2,2-bipy) ligand. Each pair of adjacent Mn(II) atoms is bridged by a CH(3)O-ip ligand, forming a helical chain running along a crystallographic 2(1) axis in the c-axis direction. These chains are decorated with 2,2′-bipy ligands on alternating sides. O—H⋯O hydrogen bonding involving the water molecules stabilizes the crystal structure. |
format | Text |
id | pubmed-2970467 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2009 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29704672010-12-30 catena-Poly[[[aqua(2,2′-bipyridine)manganese(II)]-μ-5-methoxyisophthalato-κ(3) O,O′:O′′] monohydrate] Shen, Su-Mei Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, {[Mn(C(8)H(4)O(4))(C(10)H(8)N(2))(H(2)O)]·H(2)O}(n), the Mn(II) centre is octahedrally coordinated by three O atoms from two 5-methoxyisophthalate (CH(3)O-ip) ligands, a fourth from a coordinated water molecule and two N atoms from one chelating 2,2′-bipyridine (2,2-bipy) ligand. Each pair of adjacent Mn(II) atoms is bridged by a CH(3)O-ip ligand, forming a helical chain running along a crystallographic 2(1) axis in the c-axis direction. These chains are decorated with 2,2′-bipy ligands on alternating sides. O—H⋯O hydrogen bonding involving the water molecules stabilizes the crystal structure. International Union of Crystallography 2009-09-05 /pmc/articles/PMC2970467/ /pubmed/21577709 http://dx.doi.org/10.1107/S1600536809035466 Text en © Su-Mei Shen 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Shen, Su-Mei catena-Poly[[[aqua(2,2′-bipyridine)manganese(II)]-μ-5-methoxyisophthalato-κ(3) O,O′:O′′] monohydrate] |
title |
catena-Poly[[[aqua(2,2′-bipyridine)manganese(II)]-μ-5-methoxyisophthalato-κ(3)
O,O′:O′′] monohydrate] |
title_full |
catena-Poly[[[aqua(2,2′-bipyridine)manganese(II)]-μ-5-methoxyisophthalato-κ(3)
O,O′:O′′] monohydrate] |
title_fullStr |
catena-Poly[[[aqua(2,2′-bipyridine)manganese(II)]-μ-5-methoxyisophthalato-κ(3)
O,O′:O′′] monohydrate] |
title_full_unstemmed |
catena-Poly[[[aqua(2,2′-bipyridine)manganese(II)]-μ-5-methoxyisophthalato-κ(3)
O,O′:O′′] monohydrate] |
title_short |
catena-Poly[[[aqua(2,2′-bipyridine)manganese(II)]-μ-5-methoxyisophthalato-κ(3)
O,O′:O′′] monohydrate] |
title_sort | catena-poly[[[aqua(2,2′-bipyridine)manganese(ii)]-μ-5-methoxyisophthalato-κ(3)
o,o′:o′′] monohydrate] |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2970467/ https://www.ncbi.nlm.nih.gov/pubmed/21577709 http://dx.doi.org/10.1107/S1600536809035466 |
work_keys_str_mv | AT shensumei catenapolyaqua22bipyridinemanganeseiim5methoxyisophthalatok3ooomonohydrate |