13-[4,5-Bis(methyl­sulfan­yl)-1,3-dithiol-2-yl­idene]-6-oxa-3,9,12,14-tetra­thia­bicyclo­[9.3.0]tetra­dec-1(11)-ene

In the title mol­ecule, C(14)H(18)OS(8), one O atom, two S atoms and six C atoms form an 11-membered ring with a chair-like conformation; the planes of the two five-membered rings connected by a carbon–carbon double bond form a dihedral angle of 29.97 (11)°. In the crystal, pairs of weak inter­molec...

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Detalles Bibliográficos
Autores principales: Hou, Rui-Bin, Li, Bao, Che, Tie, Yin, Bing-Zhu, Wu, Li-Xin
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2970471/
https://www.ncbi.nlm.nih.gov/pubmed/21577982
http://dx.doi.org/10.1107/S1600536809037301
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author Hou, Rui-Bin
Li, Bao
Che, Tie
Yin, Bing-Zhu
Wu, Li-Xin
author_facet Hou, Rui-Bin
Li, Bao
Che, Tie
Yin, Bing-Zhu
Wu, Li-Xin
author_sort Hou, Rui-Bin
collection PubMed
description In the title mol­ecule, C(14)H(18)OS(8), one O atom, two S atoms and six C atoms form an 11-membered ring with a chair-like conformation; the planes of the two five-membered rings connected by a carbon–carbon double bond form a dihedral angle of 29.97 (11)°. In the crystal, pairs of weak inter­molecular C—H⋯S hydrogen bonds link two mol­ecules into inversion dimers.
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spelling pubmed-29704712010-12-30 13-[4,5-Bis(methyl­sulfan­yl)-1,3-dithiol-2-yl­idene]-6-oxa-3,9,12,14-tetra­thia­bicyclo­[9.3.0]tetra­dec-1(11)-ene Hou, Rui-Bin Li, Bao Che, Tie Yin, Bing-Zhu Wu, Li-Xin Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title mol­ecule, C(14)H(18)OS(8), one O atom, two S atoms and six C atoms form an 11-membered ring with a chair-like conformation; the planes of the two five-membered rings connected by a carbon–carbon double bond form a dihedral angle of 29.97 (11)°. In the crystal, pairs of weak inter­molecular C—H⋯S hydrogen bonds link two mol­ecules into inversion dimers. International Union of Crystallography 2009-09-26 /pmc/articles/PMC2970471/ /pubmed/21577982 http://dx.doi.org/10.1107/S1600536809037301 Text en © Hou et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Hou, Rui-Bin
Li, Bao
Che, Tie
Yin, Bing-Zhu
Wu, Li-Xin
13-[4,5-Bis(methyl­sulfan­yl)-1,3-dithiol-2-yl­idene]-6-oxa-3,9,12,14-tetra­thia­bicyclo­[9.3.0]tetra­dec-1(11)-ene
title 13-[4,5-Bis(methyl­sulfan­yl)-1,3-dithiol-2-yl­idene]-6-oxa-3,9,12,14-tetra­thia­bicyclo­[9.3.0]tetra­dec-1(11)-ene
title_full 13-[4,5-Bis(methyl­sulfan­yl)-1,3-dithiol-2-yl­idene]-6-oxa-3,9,12,14-tetra­thia­bicyclo­[9.3.0]tetra­dec-1(11)-ene
title_fullStr 13-[4,5-Bis(methyl­sulfan­yl)-1,3-dithiol-2-yl­idene]-6-oxa-3,9,12,14-tetra­thia­bicyclo­[9.3.0]tetra­dec-1(11)-ene
title_full_unstemmed 13-[4,5-Bis(methyl­sulfan­yl)-1,3-dithiol-2-yl­idene]-6-oxa-3,9,12,14-tetra­thia­bicyclo­[9.3.0]tetra­dec-1(11)-ene
title_short 13-[4,5-Bis(methyl­sulfan­yl)-1,3-dithiol-2-yl­idene]-6-oxa-3,9,12,14-tetra­thia­bicyclo­[9.3.0]tetra­dec-1(11)-ene
title_sort 13-[4,5-bis(methyl­sulfan­yl)-1,3-dithiol-2-yl­idene]-6-oxa-3,9,12,14-tetra­thia­bicyclo­[9.3.0]tetra­dec-1(11)-ene
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2970471/
https://www.ncbi.nlm.nih.gov/pubmed/21577982
http://dx.doi.org/10.1107/S1600536809037301
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