Hexaaqua­iron(II) bis­[fac-tribromido­tricarbonyl­ferrate(II)]

In the title compound, [Fe(H(2)O)(6)][FeBr(3)(CO)(3)](2), both Fe atoms have an octa­hedral coordination and the bromide carbonyl complex has a fac-stereochemistry. The [Fe(H(2)O)(6)](2+) octa­hedron has point symmetry [Image: see text] and is slightly compressed along one O—Fe—O axis. The [FeBr(3)(...

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Detalles Bibliográficos
Autores principales: Becker, Eva, Kirchner, Karl, Mereiter, Kurt
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Inorganic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2970480/
https://www.ncbi.nlm.nih.gov/pubmed/21577693
http://dx.doi.org/10.1107/S1600536809036198
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author Becker, Eva
Kirchner, Karl
Mereiter, Kurt
author_facet Becker, Eva
Kirchner, Karl
Mereiter, Kurt
author_sort Becker, Eva
collection PubMed
description In the title compound, [Fe(H(2)O)(6)][FeBr(3)(CO)(3)](2), both Fe atoms have an octa­hedral coordination and the bromide carbonyl complex has a fac-stereochemistry. The [Fe(H(2)O)(6)](2+) octa­hedron has point symmetry [Image: see text] and is slightly compressed along one O—Fe—O axis. The [FeBr(3)(CO)(3)](−) anion has point symmetry 1 and mean bond lengths of Fe—Br = 2.455 (5) Å and Fe—C = 1.809 (2) Å. The cation and anion complexes are mutually linked via O—H⋯Br hydrogen bonds with O⋯Br distances of 3.340 (3) to 3.388 (3) Å.
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spelling pubmed-29704802010-12-30 Hexaaqua­iron(II) bis­[fac-tribromido­tricarbonyl­ferrate(II)] Becker, Eva Kirchner, Karl Mereiter, Kurt Acta Crystallogr Sect E Struct Rep Online Inorganic Papers In the title compound, [Fe(H(2)O)(6)][FeBr(3)(CO)(3)](2), both Fe atoms have an octa­hedral coordination and the bromide carbonyl complex has a fac-stereochemistry. The [Fe(H(2)O)(6)](2+) octa­hedron has point symmetry [Image: see text] and is slightly compressed along one O—Fe—O axis. The [FeBr(3)(CO)(3)](−) anion has point symmetry 1 and mean bond lengths of Fe—Br = 2.455 (5) Å and Fe—C = 1.809 (2) Å. The cation and anion complexes are mutually linked via O—H⋯Br hydrogen bonds with O⋯Br distances of 3.340 (3) to 3.388 (3) Å. International Union of Crystallography 2009-09-12 /pmc/articles/PMC2970480/ /pubmed/21577693 http://dx.doi.org/10.1107/S1600536809036198 Text en © Becker et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Inorganic Papers
Becker, Eva
Kirchner, Karl
Mereiter, Kurt
Hexaaqua­iron(II) bis­[fac-tribromido­tricarbonyl­ferrate(II)]
title Hexaaqua­iron(II) bis­[fac-tribromido­tricarbonyl­ferrate(II)]
title_full Hexaaqua­iron(II) bis­[fac-tribromido­tricarbonyl­ferrate(II)]
title_fullStr Hexaaqua­iron(II) bis­[fac-tribromido­tricarbonyl­ferrate(II)]
title_full_unstemmed Hexaaqua­iron(II) bis­[fac-tribromido­tricarbonyl­ferrate(II)]
title_short Hexaaqua­iron(II) bis­[fac-tribromido­tricarbonyl­ferrate(II)]
title_sort hexaaqua­iron(ii) bis­[fac-tribromido­tricarbonyl­ferrate(ii)]
topic Inorganic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2970480/
https://www.ncbi.nlm.nih.gov/pubmed/21577693
http://dx.doi.org/10.1107/S1600536809036198
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AT kirchnerkarl hexaaquaironiibisfactribromidotricarbonylferrateii
AT mereiterkurt hexaaquaironiibisfactribromidotricarbonylferrateii

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