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(E)-N′-(3,4-Dimethoxy­benzyl­idene)-2,4-dihydroxy­benzohydrazide methanol solvate

The title compound, C(16)H(16)N(2)O(5)·CH(3)OH, was obtained from a condensation reaction of 3,4-dimethoxy­benzaldehyde and 2,4-dihydroxy­benzohydrazide. The non-H atoms of the Schiff base mol­ecule are approximately coplanar (r.m.s. deviation = 0.043 Å) and the dihedral angle between the two benzen...

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Autores principales: Zhang, Qiao-Ling, Yin, Li-Zi, Deng, Xu-Ming, Liu, Song-Cai, Song, De-Guang
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2970482/
https://www.ncbi.nlm.nih.gov/pubmed/21577856
http://dx.doi.org/10.1107/S1600536809035752
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author Zhang, Qiao-Ling
Yin, Li-Zi
Deng, Xu-Ming
Liu, Song-Cai
Song, De-Guang
author_facet Zhang, Qiao-Ling
Yin, Li-Zi
Deng, Xu-Ming
Liu, Song-Cai
Song, De-Guang
author_sort Zhang, Qiao-Ling
collection PubMed
description The title compound, C(16)H(16)N(2)O(5)·CH(3)OH, was obtained from a condensation reaction of 3,4-dimethoxy­benzaldehyde and 2,4-dihydroxy­benzohydrazide. The non-H atoms of the Schiff base mol­ecule are approximately coplanar (r.m.s. deviation = 0.043 Å) and the dihedral angle between the two benzene rings is 1.6 (1)°. The mol­ecule adopts an E configuration with respect to the C=N double bond. An intra­molecular O—H⋯O hydrogen bond is observed. The Schiff base and methanol mol­ecules are linked into a two-dimensional network parallel to (10[Image: see text]) by inter­molecular N—H⋯O, O—H⋯N and O—H⋯O hydrogen bonds.
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spelling pubmed-29704822010-12-30 (E)-N′-(3,4-Dimethoxy­benzyl­idene)-2,4-dihydroxy­benzohydrazide methanol solvate Zhang, Qiao-Ling Yin, Li-Zi Deng, Xu-Ming Liu, Song-Cai Song, De-Guang Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(16)H(16)N(2)O(5)·CH(3)OH, was obtained from a condensation reaction of 3,4-dimethoxy­benzaldehyde and 2,4-dihydroxy­benzohydrazide. The non-H atoms of the Schiff base mol­ecule are approximately coplanar (r.m.s. deviation = 0.043 Å) and the dihedral angle between the two benzene rings is 1.6 (1)°. The mol­ecule adopts an E configuration with respect to the C=N double bond. An intra­molecular O—H⋯O hydrogen bond is observed. The Schiff base and methanol mol­ecules are linked into a two-dimensional network parallel to (10[Image: see text]) by inter­molecular N—H⋯O, O—H⋯N and O—H⋯O hydrogen bonds. International Union of Crystallography 2009-09-09 /pmc/articles/PMC2970482/ /pubmed/21577856 http://dx.doi.org/10.1107/S1600536809035752 Text en © Zhang et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Zhang, Qiao-Ling
Yin, Li-Zi
Deng, Xu-Ming
Liu, Song-Cai
Song, De-Guang
(E)-N′-(3,4-Dimethoxy­benzyl­idene)-2,4-dihydroxy­benzohydrazide methanol solvate
title (E)-N′-(3,4-Dimethoxy­benzyl­idene)-2,4-dihydroxy­benzohydrazide methanol solvate
title_full (E)-N′-(3,4-Dimethoxy­benzyl­idene)-2,4-dihydroxy­benzohydrazide methanol solvate
title_fullStr (E)-N′-(3,4-Dimethoxy­benzyl­idene)-2,4-dihydroxy­benzohydrazide methanol solvate
title_full_unstemmed (E)-N′-(3,4-Dimethoxy­benzyl­idene)-2,4-dihydroxy­benzohydrazide methanol solvate
title_short (E)-N′-(3,4-Dimethoxy­benzyl­idene)-2,4-dihydroxy­benzohydrazide methanol solvate
title_sort (e)-n′-(3,4-dimethoxy­benzyl­idene)-2,4-dihydroxy­benzohydrazide methanol solvate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2970482/
https://www.ncbi.nlm.nih.gov/pubmed/21577856
http://dx.doi.org/10.1107/S1600536809035752
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