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(E)-N′-(3,4-Dimethoxybenzylidene)-2,4-dihydroxybenzohydrazide methanol solvate
The title compound, C(16)H(16)N(2)O(5)·CH(3)OH, was obtained from a condensation reaction of 3,4-dimethoxybenzaldehyde and 2,4-dihydroxybenzohydrazide. The non-H atoms of the Schiff base molecule are approximately coplanar (r.m.s. deviation = 0.043 Å) and the dihedral angle between the two benzen...
Autores principales: | , , , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2009
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2970482/ https://www.ncbi.nlm.nih.gov/pubmed/21577856 http://dx.doi.org/10.1107/S1600536809035752 |
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author | Zhang, Qiao-Ling Yin, Li-Zi Deng, Xu-Ming Liu, Song-Cai Song, De-Guang |
author_facet | Zhang, Qiao-Ling Yin, Li-Zi Deng, Xu-Ming Liu, Song-Cai Song, De-Guang |
author_sort | Zhang, Qiao-Ling |
collection | PubMed |
description | The title compound, C(16)H(16)N(2)O(5)·CH(3)OH, was obtained from a condensation reaction of 3,4-dimethoxybenzaldehyde and 2,4-dihydroxybenzohydrazide. The non-H atoms of the Schiff base molecule are approximately coplanar (r.m.s. deviation = 0.043 Å) and the dihedral angle between the two benzene rings is 1.6 (1)°. The molecule adopts an E configuration with respect to the C=N double bond. An intramolecular O—H⋯O hydrogen bond is observed. The Schiff base and methanol molecules are linked into a two-dimensional network parallel to (10[Image: see text]) by intermolecular N—H⋯O, O—H⋯N and O—H⋯O hydrogen bonds. |
format | Text |
id | pubmed-2970482 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2009 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29704822010-12-30 (E)-N′-(3,4-Dimethoxybenzylidene)-2,4-dihydroxybenzohydrazide methanol solvate Zhang, Qiao-Ling Yin, Li-Zi Deng, Xu-Ming Liu, Song-Cai Song, De-Guang Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(16)H(16)N(2)O(5)·CH(3)OH, was obtained from a condensation reaction of 3,4-dimethoxybenzaldehyde and 2,4-dihydroxybenzohydrazide. The non-H atoms of the Schiff base molecule are approximately coplanar (r.m.s. deviation = 0.043 Å) and the dihedral angle between the two benzene rings is 1.6 (1)°. The molecule adopts an E configuration with respect to the C=N double bond. An intramolecular O—H⋯O hydrogen bond is observed. The Schiff base and methanol molecules are linked into a two-dimensional network parallel to (10[Image: see text]) by intermolecular N—H⋯O, O—H⋯N and O—H⋯O hydrogen bonds. International Union of Crystallography 2009-09-09 /pmc/articles/PMC2970482/ /pubmed/21577856 http://dx.doi.org/10.1107/S1600536809035752 Text en © Zhang et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Zhang, Qiao-Ling Yin, Li-Zi Deng, Xu-Ming Liu, Song-Cai Song, De-Guang (E)-N′-(3,4-Dimethoxybenzylidene)-2,4-dihydroxybenzohydrazide methanol solvate |
title | (E)-N′-(3,4-Dimethoxybenzylidene)-2,4-dihydroxybenzohydrazide methanol solvate |
title_full | (E)-N′-(3,4-Dimethoxybenzylidene)-2,4-dihydroxybenzohydrazide methanol solvate |
title_fullStr | (E)-N′-(3,4-Dimethoxybenzylidene)-2,4-dihydroxybenzohydrazide methanol solvate |
title_full_unstemmed | (E)-N′-(3,4-Dimethoxybenzylidene)-2,4-dihydroxybenzohydrazide methanol solvate |
title_short | (E)-N′-(3,4-Dimethoxybenzylidene)-2,4-dihydroxybenzohydrazide methanol solvate |
title_sort | (e)-n′-(3,4-dimethoxybenzylidene)-2,4-dihydroxybenzohydrazide methanol solvate |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2970482/ https://www.ncbi.nlm.nih.gov/pubmed/21577856 http://dx.doi.org/10.1107/S1600536809035752 |
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