Tetra­aquabis(6-carboxy-1H-benzimid­azole-5-carboxyl­ato-κN (3))nickel(II) dimethyl­formamide disolvate dihydrate

The title compound, [Ni(C(9)H(45)N(2)O(4))(2)(H(2)O)(4)]·2C(3)H(7)NO·2H(2)O, has the Ni(II) center coordinated by four water mol­ecules and two N atoms from two 1H-benzimidazole-5,6-dicarboxyl­ate ligands in an octa­hedral geometry. The mol­ecule inter­acts with the solvent water and dimethyl­formam...

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Detalles Bibliográficos
Autores principales: Wang, Hao, Song, Wen-Dong, Li, Shi-Jie, Qin, Pei-Wen, Hu, Shi-Wei
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2970488/
https://www.ncbi.nlm.nih.gov/pubmed/21577771
http://dx.doi.org/10.1107/S1600536809038069
Descripción
Sumario:The title compound, [Ni(C(9)H(45)N(2)O(4))(2)(H(2)O)(4)]·2C(3)H(7)NO·2H(2)O, has the Ni(II) center coordinated by four water mol­ecules and two N atoms from two 1H-benzimidazole-5,6-dicarboxyl­ate ligands in an octa­hedral geometry. The mol­ecule inter­acts with the solvent water and dimethyl­formamide mol­ecules through N—H⋯O and O—H⋯O hydrogen bonds to form a three-dimensional supra­molecular network. The metal atom lies on a center of inversion.

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