Tetra­aquabis(6-carboxy-1H-benzimid­azole-5-carboxyl­ato-κN (3))nickel(II) dimethyl­formamide disolvate dihydrate

The title compound, [Ni(C(9)H(45)N(2)O(4))(2)(H(2)O)(4)]·2C(3)H(7)NO·2H(2)O, has the Ni(II) center coordinated by four water mol­ecules and two N atoms from two 1H-benzimidazole-5,6-dicarboxyl­ate ligands in an octa­hedral geometry. The mol­ecule inter­acts with the solvent water and dimethyl­formam...

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Detalles Bibliográficos
Autores principales: Wang, Hao, Song, Wen-Dong, Li, Shi-Jie, Qin, Pei-Wen, Hu, Shi-Wei
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2970488/
https://www.ncbi.nlm.nih.gov/pubmed/21577771
http://dx.doi.org/10.1107/S1600536809038069
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author Wang, Hao
Song, Wen-Dong
Li, Shi-Jie
Qin, Pei-Wen
Hu, Shi-Wei
author_facet Wang, Hao
Song, Wen-Dong
Li, Shi-Jie
Qin, Pei-Wen
Hu, Shi-Wei
author_sort Wang, Hao
collection PubMed
description The title compound, [Ni(C(9)H(45)N(2)O(4))(2)(H(2)O)(4)]·2C(3)H(7)NO·2H(2)O, has the Ni(II) center coordinated by four water mol­ecules and two N atoms from two 1H-benzimidazole-5,6-dicarboxyl­ate ligands in an octa­hedral geometry. The mol­ecule inter­acts with the solvent water and dimethyl­formamide mol­ecules through N—H⋯O and O—H⋯O hydrogen bonds to form a three-dimensional supra­molecular network. The metal atom lies on a center of inversion.
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spelling pubmed-29704882010-12-30 Tetra­aquabis(6-carboxy-1H-benzimid­azole-5-carboxyl­ato-κN (3))nickel(II) dimethyl­formamide disolvate dihydrate Wang, Hao Song, Wen-Dong Li, Shi-Jie Qin, Pei-Wen Hu, Shi-Wei Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [Ni(C(9)H(45)N(2)O(4))(2)(H(2)O)(4)]·2C(3)H(7)NO·2H(2)O, has the Ni(II) center coordinated by four water mol­ecules and two N atoms from two 1H-benzimidazole-5,6-dicarboxyl­ate ligands in an octa­hedral geometry. The mol­ecule inter­acts with the solvent water and dimethyl­formamide mol­ecules through N—H⋯O and O—H⋯O hydrogen bonds to form a three-dimensional supra­molecular network. The metal atom lies on a center of inversion. International Union of Crystallography 2009-09-30 /pmc/articles/PMC2970488/ /pubmed/21577771 http://dx.doi.org/10.1107/S1600536809038069 Text en © Wang et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Wang, Hao
Song, Wen-Dong
Li, Shi-Jie
Qin, Pei-Wen
Hu, Shi-Wei
Tetra­aquabis(6-carboxy-1H-benzimid­azole-5-carboxyl­ato-κN (3))nickel(II) dimethyl­formamide disolvate dihydrate
title Tetra­aquabis(6-carboxy-1H-benzimid­azole-5-carboxyl­ato-κN (3))nickel(II) dimethyl­formamide disolvate dihydrate
title_full Tetra­aquabis(6-carboxy-1H-benzimid­azole-5-carboxyl­ato-κN (3))nickel(II) dimethyl­formamide disolvate dihydrate
title_fullStr Tetra­aquabis(6-carboxy-1H-benzimid­azole-5-carboxyl­ato-κN (3))nickel(II) dimethyl­formamide disolvate dihydrate
title_full_unstemmed Tetra­aquabis(6-carboxy-1H-benzimid­azole-5-carboxyl­ato-κN (3))nickel(II) dimethyl­formamide disolvate dihydrate
title_short Tetra­aquabis(6-carboxy-1H-benzimid­azole-5-carboxyl­ato-κN (3))nickel(II) dimethyl­formamide disolvate dihydrate
title_sort tetra­aquabis(6-carboxy-1h-benzimid­azole-5-carboxyl­ato-κn (3))nickel(ii) dimethyl­formamide disolvate dihydrate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2970488/
https://www.ncbi.nlm.nih.gov/pubmed/21577771
http://dx.doi.org/10.1107/S1600536809038069
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