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Poly[di-μ-thiocyanato-κ(2) N:S;κ(2) S:N-bis[2-(1H-1,2,3-triazol-1-yl-κN (3))pyrazine]cadmium(II)]
In the title two-dimensional coordination polymer, [Cd(NCS)(2)(C(6)H(5)N(5))(2)](n), the Cd(II) ion (site symmetry [Image: see text]) is coordinated by two N atoms from two 2-(1H-1,2,3-triazol-1-yl)pyrazine ligands and two N and two S atoms from four thiocyanate anions. The N—Cd bond lengths range...
Autores principales: | , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2009
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2970489/ https://www.ncbi.nlm.nih.gov/pubmed/21577737 http://dx.doi.org/10.1107/S1600536809036332 |
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author | Liu, Cheng Qi Xie, Long Miao Zhao, Ming Gen |
author_facet | Liu, Cheng Qi Xie, Long Miao Zhao, Ming Gen |
author_sort | Liu, Cheng Qi |
collection | PubMed |
description | In the title two-dimensional coordination polymer, [Cd(NCS)(2)(C(6)H(5)N(5))(2)](n), the Cd(II) ion (site symmetry [Image: see text]) is coordinated by two N atoms from two 2-(1H-1,2,3-triazol-1-yl)pyrazine ligands and two N and two S atoms from four thiocyanate anions. The N—Cd bond lengths range from 2.323 (2) to 2.3655 (19) Å and the S—Cd bond length is 2.7117 (7) Å. The associated cisoid angles vary from 84.99 (7) to 95.01 (7)°, indicating that the Cd(II) ion assumes a distorted octahedral geometry. In the complex, each thiocyanate anion functions as a bridging ligand, linking adjacent Cd(II) ions with a separation of 6.4919 (6) Å, resulting in the formation of a two-dimensional sheet structure in the bc plane. |
format | Text |
id | pubmed-2970489 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2009 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29704892010-12-30 Poly[di-μ-thiocyanato-κ(2) N:S;κ(2) S:N-bis[2-(1H-1,2,3-triazol-1-yl-κN (3))pyrazine]cadmium(II)] Liu, Cheng Qi Xie, Long Miao Zhao, Ming Gen Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title two-dimensional coordination polymer, [Cd(NCS)(2)(C(6)H(5)N(5))(2)](n), the Cd(II) ion (site symmetry [Image: see text]) is coordinated by two N atoms from two 2-(1H-1,2,3-triazol-1-yl)pyrazine ligands and two N and two S atoms from four thiocyanate anions. The N—Cd bond lengths range from 2.323 (2) to 2.3655 (19) Å and the S—Cd bond length is 2.7117 (7) Å. The associated cisoid angles vary from 84.99 (7) to 95.01 (7)°, indicating that the Cd(II) ion assumes a distorted octahedral geometry. In the complex, each thiocyanate anion functions as a bridging ligand, linking adjacent Cd(II) ions with a separation of 6.4919 (6) Å, resulting in the formation of a two-dimensional sheet structure in the bc plane. International Union of Crystallography 2009-09-12 /pmc/articles/PMC2970489/ /pubmed/21577737 http://dx.doi.org/10.1107/S1600536809036332 Text en © Liu et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Liu, Cheng Qi Xie, Long Miao Zhao, Ming Gen Poly[di-μ-thiocyanato-κ(2) N:S;κ(2) S:N-bis[2-(1H-1,2,3-triazol-1-yl-κN (3))pyrazine]cadmium(II)] |
title | Poly[di-μ-thiocyanato-κ(2)
N:S;κ(2)
S:N-bis[2-(1H-1,2,3-triazol-1-yl-κN
(3))pyrazine]cadmium(II)] |
title_full | Poly[di-μ-thiocyanato-κ(2)
N:S;κ(2)
S:N-bis[2-(1H-1,2,3-triazol-1-yl-κN
(3))pyrazine]cadmium(II)] |
title_fullStr | Poly[di-μ-thiocyanato-κ(2)
N:S;κ(2)
S:N-bis[2-(1H-1,2,3-triazol-1-yl-κN
(3))pyrazine]cadmium(II)] |
title_full_unstemmed | Poly[di-μ-thiocyanato-κ(2)
N:S;κ(2)
S:N-bis[2-(1H-1,2,3-triazol-1-yl-κN
(3))pyrazine]cadmium(II)] |
title_short | Poly[di-μ-thiocyanato-κ(2)
N:S;κ(2)
S:N-bis[2-(1H-1,2,3-triazol-1-yl-κN
(3))pyrazine]cadmium(II)] |
title_sort | poly[di-μ-thiocyanato-κ(2)
n:s;κ(2)
s:n-bis[2-(1h-1,2,3-triazol-1-yl-κn
(3))pyrazine]cadmium(ii)] |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2970489/ https://www.ncbi.nlm.nih.gov/pubmed/21577737 http://dx.doi.org/10.1107/S1600536809036332 |
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