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Poly[di-μ-thiocyanato-κ(2) N:S;κ(2) S:N-bis­[2-(1H-1,2,3-triazol-1-yl-κN (3))pyra­zine]cadmium(II)]

In the title two-dimensional coordination polymer, [Cd(NCS)(2)(C(6)H(5)N(5))(2)](n), the Cd(II) ion (site symmetry [Image: see text]) is coordinated by two N atoms from two 2-(1H-1,2,3-triazol-1-yl)pyrazine ligands and two N and two S atoms from four thio­cyanate anions. The N—Cd bond lengths range...

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Detalles Bibliográficos
Autores principales: Liu, Cheng Qi, Xie, Long Miao, Zhao, Ming Gen
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2970489/
https://www.ncbi.nlm.nih.gov/pubmed/21577737
http://dx.doi.org/10.1107/S1600536809036332
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author Liu, Cheng Qi
Xie, Long Miao
Zhao, Ming Gen
author_facet Liu, Cheng Qi
Xie, Long Miao
Zhao, Ming Gen
author_sort Liu, Cheng Qi
collection PubMed
description In the title two-dimensional coordination polymer, [Cd(NCS)(2)(C(6)H(5)N(5))(2)](n), the Cd(II) ion (site symmetry [Image: see text]) is coordinated by two N atoms from two 2-(1H-1,2,3-triazol-1-yl)pyrazine ligands and two N and two S atoms from four thio­cyanate anions. The N—Cd bond lengths range from 2.323 (2) to 2.3655 (19) Å and the S—Cd bond length is 2.7117 (7) Å. The associated cisoid angles vary from 84.99 (7) to 95.01 (7)°, indicating that the Cd(II) ion assumes a distorted octa­hedral geometry. In the complex, each thio­cyanate anion functions as a bridging ligand, linking adjacent Cd(II) ions with a separation of 6.4919 (6) Å, resulting in the formation of a two-dimensional sheet structure in the bc plane.
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spelling pubmed-29704892010-12-30 Poly[di-μ-thiocyanato-κ(2) N:S;κ(2) S:N-bis­[2-(1H-1,2,3-triazol-1-yl-κN (3))pyra­zine]cadmium(II)] Liu, Cheng Qi Xie, Long Miao Zhao, Ming Gen Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title two-dimensional coordination polymer, [Cd(NCS)(2)(C(6)H(5)N(5))(2)](n), the Cd(II) ion (site symmetry [Image: see text]) is coordinated by two N atoms from two 2-(1H-1,2,3-triazol-1-yl)pyrazine ligands and two N and two S atoms from four thio­cyanate anions. The N—Cd bond lengths range from 2.323 (2) to 2.3655 (19) Å and the S—Cd bond length is 2.7117 (7) Å. The associated cisoid angles vary from 84.99 (7) to 95.01 (7)°, indicating that the Cd(II) ion assumes a distorted octa­hedral geometry. In the complex, each thio­cyanate anion functions as a bridging ligand, linking adjacent Cd(II) ions with a separation of 6.4919 (6) Å, resulting in the formation of a two-dimensional sheet structure in the bc plane. International Union of Crystallography 2009-09-12 /pmc/articles/PMC2970489/ /pubmed/21577737 http://dx.doi.org/10.1107/S1600536809036332 Text en © Liu et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Liu, Cheng Qi
Xie, Long Miao
Zhao, Ming Gen
Poly[di-μ-thiocyanato-κ(2) N:S;κ(2) S:N-bis­[2-(1H-1,2,3-triazol-1-yl-κN (3))pyra­zine]cadmium(II)]
title Poly[di-μ-thiocyanato-κ(2) N:S;κ(2) S:N-bis­[2-(1H-1,2,3-triazol-1-yl-κN (3))pyra­zine]cadmium(II)]
title_full Poly[di-μ-thiocyanato-κ(2) N:S;κ(2) S:N-bis­[2-(1H-1,2,3-triazol-1-yl-κN (3))pyra­zine]cadmium(II)]
title_fullStr Poly[di-μ-thiocyanato-κ(2) N:S;κ(2) S:N-bis­[2-(1H-1,2,3-triazol-1-yl-κN (3))pyra­zine]cadmium(II)]
title_full_unstemmed Poly[di-μ-thiocyanato-κ(2) N:S;κ(2) S:N-bis­[2-(1H-1,2,3-triazol-1-yl-κN (3))pyra­zine]cadmium(II)]
title_short Poly[di-μ-thiocyanato-κ(2) N:S;κ(2) S:N-bis­[2-(1H-1,2,3-triazol-1-yl-κN (3))pyra­zine]cadmium(II)]
title_sort poly[di-μ-thiocyanato-κ(2) n:s;κ(2) s:n-bis­[2-(1h-1,2,3-triazol-1-yl-κn (3))pyra­zine]cadmium(ii)]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2970489/
https://www.ncbi.nlm.nih.gov/pubmed/21577737
http://dx.doi.org/10.1107/S1600536809036332
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