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5-(4-Bromo­anilinomethyl­ene)-2,2-dimethyl-1,3-dioxane-4,6-dione

In the title compound, C(13)H(12)BrNO(4), the dihedral angles between the amino­methyl­ene group and the dioxane ring and between the benzyl ring and the amino­methyl­ene unit are 7.96 (4) and 12.15 (4)°, respectively. The dioxane ring shows a half-boat conformation, in which the C atom between the...

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Detalles Bibliográficos
Autores principales: Shi, Jian-You, Yang, Jin-Cheng, Yang, Jin-Liang
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2970495/
https://www.ncbi.nlm.nih.gov/pubmed/21577913
http://dx.doi.org/10.1107/S1600536809035776
Descripción
Sumario:In the title compound, C(13)H(12)BrNO(4), the dihedral angles between the amino­methyl­ene group and the dioxane ring and between the benzyl ring and the amino­methyl­ene unit are 7.96 (4) and 12.15 (4)°, respectively. The dioxane ring shows a half-boat conformation, in which the C atom between the dioxane ring O atoms is 0.460 (8) Å out of the plane through the remaining ring atoms. An intra­molecular N—H⋯O hydrogen bond may stabilize the planar conformation of the mol­ecule. An inter­molecular C—H⋯O inter­action is also present.