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cis-Bis[(1-adamantylmeth­yl)amine-κN]­dichloridoplatinum(II) N,N-dimethyl­formamide solvate

The asymmetric unit of the title compound {systematic name: cis-dichloridobis[(3,7-dimethylbicyclo­[3.3.1]non-1-ylmeth­yl)­amine-κN]platinum(II) N,N-dimethyl­formamide solvate}, [PtCl(2)(C(11)H(19)N)(2)]·C(3)H(7)NO, consists of two metrically similar Pt complexes and two dimethyl­formamide solvent m...

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Detalles Bibliográficos
Autores principales: Rochon, Fernande D., Tessier, Christian
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2970952/
https://www.ncbi.nlm.nih.gov/pubmed/21578064
http://dx.doi.org/10.1107/S1600536809037982
Descripción
Sumario:The asymmetric unit of the title compound {systematic name: cis-dichloridobis[(3,7-dimethylbicyclo­[3.3.1]non-1-ylmeth­yl)­amine-κN]platinum(II) N,N-dimethyl­formamide solvate}, [PtCl(2)(C(11)H(19)N)(2)]·C(3)H(7)NO, consists of two metrically similar Pt complexes and two dimethyl­formamide solvent mol­ecules. Each Pt(II) center is coordinated by the amine groups of two (1-adamantylmeth­yl)amine ligands and two Cl atoms in a cis-square-planar arrangement. The Pt(II) centers lie slightly outside [0.031 (4) and 0.038 (4) Å] the coordination planes. The N—Pt—N and Cl—Pt—Cl angles [92.1 (4)–92.30 (11)°] are slightly more open than the N—Pt—Cl angles [87.3 (3)–88.3 (3)°]. N—H⋯O and N—H⋯Cl inter­molecular hydrogen bonds are observed, forming two discrete pairs of complexes and solvent mol­ecules.