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cis-Bis[(1-adamantylmethyl)amine-κN]dichloridoplatinum(II) N,N-dimethylformamide solvate
The asymmetric unit of the title compound {systematic name: cis-dichloridobis[(3,7-dimethylbicyclo[3.3.1]non-1-ylmethyl)amine-κN]platinum(II) N,N-dimethylformamide solvate}, [PtCl(2)(C(11)H(19)N)(2)]·C(3)H(7)NO, consists of two metrically similar Pt complexes and two dimethylformamide solvent m...
Autores principales: | , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2009
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2970952/ https://www.ncbi.nlm.nih.gov/pubmed/21578064 http://dx.doi.org/10.1107/S1600536809037982 |
Sumario: | The asymmetric unit of the title compound {systematic name: cis-dichloridobis[(3,7-dimethylbicyclo[3.3.1]non-1-ylmethyl)amine-κN]platinum(II) N,N-dimethylformamide solvate}, [PtCl(2)(C(11)H(19)N)(2)]·C(3)H(7)NO, consists of two metrically similar Pt complexes and two dimethylformamide solvent molecules. Each Pt(II) center is coordinated by the amine groups of two (1-adamantylmethyl)amine ligands and two Cl atoms in a cis-square-planar arrangement. The Pt(II) centers lie slightly outside [0.031 (4) and 0.038 (4) Å] the coordination planes. The N—Pt—N and Cl—Pt—Cl angles [92.1 (4)–92.30 (11)°] are slightly more open than the N—Pt—Cl angles [87.3 (3)–88.3 (3)°]. N—H⋯O and N—H⋯Cl intermolecular hydrogen bonds are observed, forming two discrete pairs of complexes and solvent molecules. |
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