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cis-Bis[(1-adamantylmeth­yl)amine-κN]­dichloridoplatinum(II) N,N-dimethyl­formamide solvate

The asymmetric unit of the title compound {systematic name: cis-dichloridobis[(3,7-dimethylbicyclo­[3.3.1]non-1-ylmeth­yl)­amine-κN]platinum(II) N,N-dimethyl­formamide solvate}, [PtCl(2)(C(11)H(19)N)(2)]·C(3)H(7)NO, consists of two metrically similar Pt complexes and two dimethyl­formamide solvent m...

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Autores principales: Rochon, Fernande D., Tessier, Christian
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2970952/
https://www.ncbi.nlm.nih.gov/pubmed/21578064
http://dx.doi.org/10.1107/S1600536809037982
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author Rochon, Fernande D.
Tessier, Christian
author_facet Rochon, Fernande D.
Tessier, Christian
author_sort Rochon, Fernande D.
collection PubMed
description The asymmetric unit of the title compound {systematic name: cis-dichloridobis[(3,7-dimethylbicyclo­[3.3.1]non-1-ylmeth­yl)­amine-κN]platinum(II) N,N-dimethyl­formamide solvate}, [PtCl(2)(C(11)H(19)N)(2)]·C(3)H(7)NO, consists of two metrically similar Pt complexes and two dimethyl­formamide solvent mol­ecules. Each Pt(II) center is coordinated by the amine groups of two (1-adamantylmeth­yl)amine ligands and two Cl atoms in a cis-square-planar arrangement. The Pt(II) centers lie slightly outside [0.031 (4) and 0.038 (4) Å] the coordination planes. The N—Pt—N and Cl—Pt—Cl angles [92.1 (4)–92.30 (11)°] are slightly more open than the N—Pt—Cl angles [87.3 (3)–88.3 (3)°]. N—H⋯O and N—H⋯Cl inter­molecular hydrogen bonds are observed, forming two discrete pairs of complexes and solvent mol­ecules.
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spelling pubmed-29709522010-12-30 cis-Bis[(1-adamantylmeth­yl)amine-κN]­dichloridoplatinum(II) N,N-dimethyl­formamide solvate Rochon, Fernande D. Tessier, Christian Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The asymmetric unit of the title compound {systematic name: cis-dichloridobis[(3,7-dimethylbicyclo­[3.3.1]non-1-ylmeth­yl)­amine-κN]platinum(II) N,N-dimethyl­formamide solvate}, [PtCl(2)(C(11)H(19)N)(2)]·C(3)H(7)NO, consists of two metrically similar Pt complexes and two dimethyl­formamide solvent mol­ecules. Each Pt(II) center is coordinated by the amine groups of two (1-adamantylmeth­yl)amine ligands and two Cl atoms in a cis-square-planar arrangement. The Pt(II) centers lie slightly outside [0.031 (4) and 0.038 (4) Å] the coordination planes. The N—Pt—N and Cl—Pt—Cl angles [92.1 (4)–92.30 (11)°] are slightly more open than the N—Pt—Cl angles [87.3 (3)–88.3 (3)°]. N—H⋯O and N—H⋯Cl inter­molecular hydrogen bonds are observed, forming two discrete pairs of complexes and solvent mol­ecules. International Union of Crystallography 2009-10-03 /pmc/articles/PMC2970952/ /pubmed/21578064 http://dx.doi.org/10.1107/S1600536809037982 Text en © Rochon and Tessier 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Rochon, Fernande D.
Tessier, Christian
cis-Bis[(1-adamantylmeth­yl)amine-κN]­dichloridoplatinum(II) N,N-dimethyl­formamide solvate
title cis-Bis[(1-adamantylmeth­yl)amine-κN]­dichloridoplatinum(II) N,N-dimethyl­formamide solvate
title_full cis-Bis[(1-adamantylmeth­yl)amine-κN]­dichloridoplatinum(II) N,N-dimethyl­formamide solvate
title_fullStr cis-Bis[(1-adamantylmeth­yl)amine-κN]­dichloridoplatinum(II) N,N-dimethyl­formamide solvate
title_full_unstemmed cis-Bis[(1-adamantylmeth­yl)amine-κN]­dichloridoplatinum(II) N,N-dimethyl­formamide solvate
title_short cis-Bis[(1-adamantylmeth­yl)amine-κN]­dichloridoplatinum(II) N,N-dimethyl­formamide solvate
title_sort cis-bis[(1-adamantylmeth­yl)amine-κn]­dichloridoplatinum(ii) n,n-dimethyl­formamide solvate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2970952/
https://www.ncbi.nlm.nih.gov/pubmed/21578064
http://dx.doi.org/10.1107/S1600536809037982
work_keys_str_mv AT rochonfernanded cisbis1adamantylmethylaminekndichloridoplatinumiinndimethylformamidesolvate
AT tessierchristian cisbis1adamantylmethylaminekndichloridoplatinumiinndimethylformamidesolvate