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cis-Bis[(1-adamantylmethyl)amine-κN]dichloridoplatinum(II) N,N-dimethylformamide solvate
The asymmetric unit of the title compound {systematic name: cis-dichloridobis[(3,7-dimethylbicyclo[3.3.1]non-1-ylmethyl)amine-κN]platinum(II) N,N-dimethylformamide solvate}, [PtCl(2)(C(11)H(19)N)(2)]·C(3)H(7)NO, consists of two metrically similar Pt complexes and two dimethylformamide solvent m...
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2009
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2970952/ https://www.ncbi.nlm.nih.gov/pubmed/21578064 http://dx.doi.org/10.1107/S1600536809037982 |
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author | Rochon, Fernande D. Tessier, Christian |
author_facet | Rochon, Fernande D. Tessier, Christian |
author_sort | Rochon, Fernande D. |
collection | PubMed |
description | The asymmetric unit of the title compound {systematic name: cis-dichloridobis[(3,7-dimethylbicyclo[3.3.1]non-1-ylmethyl)amine-κN]platinum(II) N,N-dimethylformamide solvate}, [PtCl(2)(C(11)H(19)N)(2)]·C(3)H(7)NO, consists of two metrically similar Pt complexes and two dimethylformamide solvent molecules. Each Pt(II) center is coordinated by the amine groups of two (1-adamantylmethyl)amine ligands and two Cl atoms in a cis-square-planar arrangement. The Pt(II) centers lie slightly outside [0.031 (4) and 0.038 (4) Å] the coordination planes. The N—Pt—N and Cl—Pt—Cl angles [92.1 (4)–92.30 (11)°] are slightly more open than the N—Pt—Cl angles [87.3 (3)–88.3 (3)°]. N—H⋯O and N—H⋯Cl intermolecular hydrogen bonds are observed, forming two discrete pairs of complexes and solvent molecules. |
format | Text |
id | pubmed-2970952 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2009 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29709522010-12-30 cis-Bis[(1-adamantylmethyl)amine-κN]dichloridoplatinum(II) N,N-dimethylformamide solvate Rochon, Fernande D. Tessier, Christian Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The asymmetric unit of the title compound {systematic name: cis-dichloridobis[(3,7-dimethylbicyclo[3.3.1]non-1-ylmethyl)amine-κN]platinum(II) N,N-dimethylformamide solvate}, [PtCl(2)(C(11)H(19)N)(2)]·C(3)H(7)NO, consists of two metrically similar Pt complexes and two dimethylformamide solvent molecules. Each Pt(II) center is coordinated by the amine groups of two (1-adamantylmethyl)amine ligands and two Cl atoms in a cis-square-planar arrangement. The Pt(II) centers lie slightly outside [0.031 (4) and 0.038 (4) Å] the coordination planes. The N—Pt—N and Cl—Pt—Cl angles [92.1 (4)–92.30 (11)°] are slightly more open than the N—Pt—Cl angles [87.3 (3)–88.3 (3)°]. N—H⋯O and N—H⋯Cl intermolecular hydrogen bonds are observed, forming two discrete pairs of complexes and solvent molecules. International Union of Crystallography 2009-10-03 /pmc/articles/PMC2970952/ /pubmed/21578064 http://dx.doi.org/10.1107/S1600536809037982 Text en © Rochon and Tessier 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Rochon, Fernande D. Tessier, Christian cis-Bis[(1-adamantylmethyl)amine-κN]dichloridoplatinum(II) N,N-dimethylformamide solvate |
title |
cis-Bis[(1-adamantylmethyl)amine-κN]dichloridoplatinum(II) N,N-dimethylformamide solvate |
title_full |
cis-Bis[(1-adamantylmethyl)amine-κN]dichloridoplatinum(II) N,N-dimethylformamide solvate |
title_fullStr |
cis-Bis[(1-adamantylmethyl)amine-κN]dichloridoplatinum(II) N,N-dimethylformamide solvate |
title_full_unstemmed |
cis-Bis[(1-adamantylmethyl)amine-κN]dichloridoplatinum(II) N,N-dimethylformamide solvate |
title_short |
cis-Bis[(1-adamantylmethyl)amine-κN]dichloridoplatinum(II) N,N-dimethylformamide solvate |
title_sort | cis-bis[(1-adamantylmethyl)amine-κn]dichloridoplatinum(ii) n,n-dimethylformamide solvate |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2970952/ https://www.ncbi.nlm.nih.gov/pubmed/21578064 http://dx.doi.org/10.1107/S1600536809037982 |
work_keys_str_mv | AT rochonfernanded cisbis1adamantylmethylaminekndichloridoplatinumiinndimethylformamidesolvate AT tessierchristian cisbis1adamantylmethylaminekndichloridoplatinumiinndimethylformamidesolvate |