Poly[[triaqua­(μ(3)-pyridine-2,4,6-tri­car­boxyl­ato)gadolinium(III)] monohydrate]

The title compound, {[Gd(C(8)H(2)NO(6))(H(2)O)(3)]·H(2)O}(n), was obtained in water under hydro­thermal conditions. The Gd(III) ions are nine-coordinated by two O and one N atoms from one pyridine-2,4,6-tricarboxyl­ate ligand, two O atoms from another ligand, one O atom from a third ligand and three...

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Detalles Bibliográficos
Autores principales: Wang, Hong-Sheng, Zhang, Wan-Qiang
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2970953/
https://www.ncbi.nlm.nih.gov/pubmed/21578044
http://dx.doi.org/10.1107/S1600536809038793
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author Wang, Hong-Sheng
Zhang, Wan-Qiang
author_facet Wang, Hong-Sheng
Zhang, Wan-Qiang
author_sort Wang, Hong-Sheng
collection PubMed
description The title compound, {[Gd(C(8)H(2)NO(6))(H(2)O)(3)]·H(2)O}(n), was obtained in water under hydro­thermal conditions. The Gd(III) ions are nine-coordinated by two O and one N atoms from one pyridine-2,4,6-tricarboxyl­ate ligand, two O atoms from another ligand, one O atom from a third ligand and three coordinated water mol­ecules. Each ligand binds three metal centers. Two-dimensional layers are formed through the Gd—O bonds and the layers are linked by O—H⋯O hydrogen bonds, forming a three-dimensional network.
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spelling pubmed-29709532010-12-30 Poly[[triaqua­(μ(3)-pyridine-2,4,6-tri­car­boxyl­ato)gadolinium(III)] monohydrate] Wang, Hong-Sheng Zhang, Wan-Qiang Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, {[Gd(C(8)H(2)NO(6))(H(2)O)(3)]·H(2)O}(n), was obtained in water under hydro­thermal conditions. The Gd(III) ions are nine-coordinated by two O and one N atoms from one pyridine-2,4,6-tricarboxyl­ate ligand, two O atoms from another ligand, one O atom from a third ligand and three coordinated water mol­ecules. Each ligand binds three metal centers. Two-dimensional layers are formed through the Gd—O bonds and the layers are linked by O—H⋯O hydrogen bonds, forming a three-dimensional network. International Union of Crystallography 2009-10-03 /pmc/articles/PMC2970953/ /pubmed/21578044 http://dx.doi.org/10.1107/S1600536809038793 Text en © Wang and Zhang 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Wang, Hong-Sheng
Zhang, Wan-Qiang
Poly[[triaqua­(μ(3)-pyridine-2,4,6-tri­car­boxyl­ato)gadolinium(III)] monohydrate]
title Poly[[triaqua­(μ(3)-pyridine-2,4,6-tri­car­boxyl­ato)gadolinium(III)] monohydrate]
title_full Poly[[triaqua­(μ(3)-pyridine-2,4,6-tri­car­boxyl­ato)gadolinium(III)] monohydrate]
title_fullStr Poly[[triaqua­(μ(3)-pyridine-2,4,6-tri­car­boxyl­ato)gadolinium(III)] monohydrate]
title_full_unstemmed Poly[[triaqua­(μ(3)-pyridine-2,4,6-tri­car­boxyl­ato)gadolinium(III)] monohydrate]
title_short Poly[[triaqua­(μ(3)-pyridine-2,4,6-tri­car­boxyl­ato)gadolinium(III)] monohydrate]
title_sort poly[[triaqua­(μ(3)-pyridine-2,4,6-tri­car­boxyl­ato)gadolinium(iii)] monohydrate]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2970953/
https://www.ncbi.nlm.nih.gov/pubmed/21578044
http://dx.doi.org/10.1107/S1600536809038793
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