{2-Hydr­oxy-N′-[1-(2-oxidophenyl)ethyl­idene]benzohydrazidato}morpholinecopper(II)

The Cu(II) ion in the title complex, [Cu(C(15)H(12)N(2)O(3))(C(4)H(9)NO)], is coordinated by one carbonyl O atom, one hydrazine N atom and one phenolate O atom from the doubly deprotonated tridentate ligand and one N atom from a morpholine mol­ecule, forming a distorted trans-CuN(2)O(2) square-plana...

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Detalles Bibliográficos
Autores principales: Lin, Song-Zhu, Jia, Ruo-Kun, Yuan, Yan-Lin, Zhan, Peng
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2970954/
https://www.ncbi.nlm.nih.gov/pubmed/21578158
http://dx.doi.org/10.1107/S1600536809042810
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author Lin, Song-Zhu
Jia, Ruo-Kun
Yuan, Yan-Lin
Zhan, Peng
author_facet Lin, Song-Zhu
Jia, Ruo-Kun
Yuan, Yan-Lin
Zhan, Peng
author_sort Lin, Song-Zhu
collection PubMed
description The Cu(II) ion in the title complex, [Cu(C(15)H(12)N(2)O(3))(C(4)H(9)NO)], is coordinated by one carbonyl O atom, one hydrazine N atom and one phenolate O atom from the doubly deprotonated tridentate ligand and one N atom from a morpholine mol­ecule, forming a distorted trans-CuN(2)O(2) square-planar coordination geometry. An intra­molecular O—H⋯N hydrogen bond occurs within the ligand, generating an S(6) ring.
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spelling pubmed-29709542010-12-30 {2-Hydr­oxy-N′-[1-(2-oxidophenyl)ethyl­idene]benzohydrazidato}morpholinecopper(II) Lin, Song-Zhu Jia, Ruo-Kun Yuan, Yan-Lin Zhan, Peng Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The Cu(II) ion in the title complex, [Cu(C(15)H(12)N(2)O(3))(C(4)H(9)NO)], is coordinated by one carbonyl O atom, one hydrazine N atom and one phenolate O atom from the doubly deprotonated tridentate ligand and one N atom from a morpholine mol­ecule, forming a distorted trans-CuN(2)O(2) square-planar coordination geometry. An intra­molecular O—H⋯N hydrogen bond occurs within the ligand, generating an S(6) ring. International Union of Crystallography 2009-10-23 /pmc/articles/PMC2970954/ /pubmed/21578158 http://dx.doi.org/10.1107/S1600536809042810 Text en © Lin et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Lin, Song-Zhu
Jia, Ruo-Kun
Yuan, Yan-Lin
Zhan, Peng
{2-Hydr­oxy-N′-[1-(2-oxidophenyl)ethyl­idene]benzohydrazidato}morpholinecopper(II)
title {2-Hydr­oxy-N′-[1-(2-oxidophenyl)ethyl­idene]benzohydrazidato}morpholinecopper(II)
title_full {2-Hydr­oxy-N′-[1-(2-oxidophenyl)ethyl­idene]benzohydrazidato}morpholinecopper(II)
title_fullStr {2-Hydr­oxy-N′-[1-(2-oxidophenyl)ethyl­idene]benzohydrazidato}morpholinecopper(II)
title_full_unstemmed {2-Hydr­oxy-N′-[1-(2-oxidophenyl)ethyl­idene]benzohydrazidato}morpholinecopper(II)
title_short {2-Hydr­oxy-N′-[1-(2-oxidophenyl)ethyl­idene]benzohydrazidato}morpholinecopper(II)
title_sort {2-hydr­oxy-n′-[1-(2-oxidophenyl)ethyl­idene]benzohydrazidato}morpholinecopper(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2970954/
https://www.ncbi.nlm.nih.gov/pubmed/21578158
http://dx.doi.org/10.1107/S1600536809042810
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AT jiaruokun 2hydroxyn12oxidophenylethylidenebenzohydrazidatomorpholinecopperii
AT yuanyanlin 2hydroxyn12oxidophenylethylidenebenzohydrazidatomorpholinecopperii
AT zhanpeng 2hydroxyn12oxidophenylethylidenebenzohydrazidatomorpholinecopperii

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