Bis(isonicotinamide-κN (1))bis­[4-(methyl­amino)benzoato]zinc(II) monohydrate

In the title Zn(II) complex, [Zn(C(8)H(8)NO(2))(2)(C(6)H(6)N(2)O)(2)]·H(2)O, the Zn atom is coordinated by two 4-methyl­amino­benzoate (MAB) and two isonicotinamide (INA) ligands in a distorted trigonal-bipyramidal geometry; one of the MAB ions acts as a bidentate ligand while the other MAB and the...

Descripción completa

Detalles Bibliográficos
Autores principales: Hökelek, Tuncer, Dal, Hakan, Tercan, Barış, Aybirdi, Özgür, Necefoğlu, Hacali
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2970957/
https://www.ncbi.nlm.nih.gov/pubmed/21578119
http://dx.doi.org/10.1107/S1600536809041208
_version_ 1782190512119218176
author Hökelek, Tuncer
Dal, Hakan
Tercan, Barış
Aybirdi, Özgür
Necefoğlu, Hacali
author_facet Hökelek, Tuncer
Dal, Hakan
Tercan, Barış
Aybirdi, Özgür
Necefoğlu, Hacali
author_sort Hökelek, Tuncer
collection PubMed
description In the title Zn(II) complex, [Zn(C(8)H(8)NO(2))(2)(C(6)H(6)N(2)O)(2)]·H(2)O, the Zn atom is coordinated by two 4-methyl­amino­benzoate (MAB) and two isonicotinamide (INA) ligands in a distorted trigonal-bipyramidal geometry; one of the MAB ions acts as a bidentate ligand while the other MAB and the two INA are monodentate ligands. The dihedral angles between the carboxyl groups and the adjacent benzene rings are 8.52 (22) and 5.10 (14)°. In the crystal, inter­molecular O—H⋯O and N—H⋯O hydrogen bonding links the mol­ecules into a supra­molecular structure. Weak inter­molecular C—H⋯O inter­actions are also present.
format Text
id pubmed-2970957
institution National Center for Biotechnology Information
language English
publishDate 2009
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-29709572010-12-30 Bis(isonicotinamide-κN (1))bis­[4-(methyl­amino)benzoato]zinc(II) monohydrate Hökelek, Tuncer Dal, Hakan Tercan, Barış Aybirdi, Özgür Necefoğlu, Hacali Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title Zn(II) complex, [Zn(C(8)H(8)NO(2))(2)(C(6)H(6)N(2)O)(2)]·H(2)O, the Zn atom is coordinated by two 4-methyl­amino­benzoate (MAB) and two isonicotinamide (INA) ligands in a distorted trigonal-bipyramidal geometry; one of the MAB ions acts as a bidentate ligand while the other MAB and the two INA are monodentate ligands. The dihedral angles between the carboxyl groups and the adjacent benzene rings are 8.52 (22) and 5.10 (14)°. In the crystal, inter­molecular O—H⋯O and N—H⋯O hydrogen bonding links the mol­ecules into a supra­molecular structure. Weak inter­molecular C—H⋯O inter­actions are also present. International Union of Crystallography 2009-10-17 /pmc/articles/PMC2970957/ /pubmed/21578119 http://dx.doi.org/10.1107/S1600536809041208 Text en © Hökelek et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Hökelek, Tuncer
Dal, Hakan
Tercan, Barış
Aybirdi, Özgür
Necefoğlu, Hacali
Bis(isonicotinamide-κN (1))bis­[4-(methyl­amino)benzoato]zinc(II) monohydrate
title Bis(isonicotinamide-κN (1))bis­[4-(methyl­amino)benzoato]zinc(II) monohydrate
title_full Bis(isonicotinamide-κN (1))bis­[4-(methyl­amino)benzoato]zinc(II) monohydrate
title_fullStr Bis(isonicotinamide-κN (1))bis­[4-(methyl­amino)benzoato]zinc(II) monohydrate
title_full_unstemmed Bis(isonicotinamide-κN (1))bis­[4-(methyl­amino)benzoato]zinc(II) monohydrate
title_short Bis(isonicotinamide-κN (1))bis­[4-(methyl­amino)benzoato]zinc(II) monohydrate
title_sort bis(isonicotinamide-κn (1))bis­[4-(methyl­amino)benzoato]zinc(ii) monohydrate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2970957/
https://www.ncbi.nlm.nih.gov/pubmed/21578119
http://dx.doi.org/10.1107/S1600536809041208
work_keys_str_mv AT hokelektuncer bisisonicotinamidekn1bis4methylaminobenzoatozinciimonohydrate
AT dalhakan bisisonicotinamidekn1bis4methylaminobenzoatozinciimonohydrate
AT tercanbarıs bisisonicotinamidekn1bis4methylaminobenzoatozinciimonohydrate
AT aybirdiozgur bisisonicotinamidekn1bis4methylaminobenzoatozinciimonohydrate
AT necefogluhacali bisisonicotinamidekn1bis4methylaminobenzoatozinciimonohydrate

Ejemplares similares