[N-(2-Hydroxy­ethyl)ethyl­enediamine]oxalatocopper(II)

In the title mononuclear copper(II) compound, [Cu(C(2)O(4))(C(4)H(12)N(2)O)], the Cu(II) ion has a slightly distorted square-pyramidal geometry, with a tridentate N-(2-hydroxy­ethyl)ethyl­enediamine (HydEt-en) and a bidentate oxalate (ox) ligand. The N atoms of the HydEt-en ligand and the O atoms of...

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Autores principales: Paşaoğlu, Hümeyra, Kaştaş, Gökhan, Yeşilel, Okan Z., Yıldırım, M. Hakkı
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2970959/
https://www.ncbi.nlm.nih.gov/pubmed/21578094
http://dx.doi.org/10.1107/S1600536809040264
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author Paşaoğlu, Hümeyra
Kaştaş, Gökhan
Yeşilel, Okan Z.
Yıldırım, M. Hakkı
author_facet Paşaoğlu, Hümeyra
Kaştaş, Gökhan
Yeşilel, Okan Z.
Yıldırım, M. Hakkı
author_sort Paşaoğlu, Hümeyra
collection PubMed
description In the title mononuclear copper(II) compound, [Cu(C(2)O(4))(C(4)H(12)N(2)O)], the Cu(II) ion has a slightly distorted square-pyramidal geometry, with a tridentate N-(2-hydroxy­ethyl)ethyl­enediamine (HydEt-en) and a bidentate oxalate (ox) ligand. The N atoms of the HydEt-en ligand and the O atoms of ox ligand form the basal plane, while the O atom of the ethanol group of the HydEt-en ligand is located in the axial position. The complex mol­ecules participate in a supra­molecular assembly through N—H⋯O and O—H⋯O hydrogen bonds between HydEt-en and ox ligands.
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spelling pubmed-29709592010-12-30 [N-(2-Hydroxy­ethyl)ethyl­enediamine]oxalatocopper(II) Paşaoğlu, Hümeyra Kaştaş, Gökhan Yeşilel, Okan Z. Yıldırım, M. Hakkı Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title mononuclear copper(II) compound, [Cu(C(2)O(4))(C(4)H(12)N(2)O)], the Cu(II) ion has a slightly distorted square-pyramidal geometry, with a tridentate N-(2-hydroxy­ethyl)ethyl­enediamine (HydEt-en) and a bidentate oxalate (ox) ligand. The N atoms of the HydEt-en ligand and the O atoms of ox ligand form the basal plane, while the O atom of the ethanol group of the HydEt-en ligand is located in the axial position. The complex mol­ecules participate in a supra­molecular assembly through N—H⋯O and O—H⋯O hydrogen bonds between HydEt-en and ox ligands. International Union of Crystallography 2009-10-10 /pmc/articles/PMC2970959/ /pubmed/21578094 http://dx.doi.org/10.1107/S1600536809040264 Text en © Paşaoğlu et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Paşaoğlu, Hümeyra
Kaştaş, Gökhan
Yeşilel, Okan Z.
Yıldırım, M. Hakkı
[N-(2-Hydroxy­ethyl)ethyl­enediamine]oxalatocopper(II)
title [N-(2-Hydroxy­ethyl)ethyl­enediamine]oxalatocopper(II)
title_full [N-(2-Hydroxy­ethyl)ethyl­enediamine]oxalatocopper(II)
title_fullStr [N-(2-Hydroxy­ethyl)ethyl­enediamine]oxalatocopper(II)
title_full_unstemmed [N-(2-Hydroxy­ethyl)ethyl­enediamine]oxalatocopper(II)
title_short [N-(2-Hydroxy­ethyl)ethyl­enediamine]oxalatocopper(II)
title_sort [n-(2-hydroxy­ethyl)ethyl­enediamine]oxalatocopper(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2970959/
https://www.ncbi.nlm.nih.gov/pubmed/21578094
http://dx.doi.org/10.1107/S1600536809040264
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AT kastasgokhan n2hydroxyethylethylenediamineoxalatocopperii
AT yesilelokanz n2hydroxyethylethylenediamineoxalatocopperii
AT yıldırımmhakkı n2hydroxyethylethylenediamineoxalatocopperii

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