[2-(3,5-Dimethyl-1H-pyrazol-1-yl-κN (2))-1,10-phenanthroline-κ(2) N,N′]bis­(thio­cyanato-κN)cadmium(II)

In the title complex, [Cd(NCS)(2)(C(17)H(14)N(4))], the Cd(II) ion is in a distorted trigonal-bipyramidal CdN(5) coordination geometry. In the crystal structure, there is a π–π stacking inter­action involving a pyrazole ring and a symmetry-related pyridine ring with a centroid–centroid distance of 3...

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Detalles Bibliográficos
Autores principales: Wang, Yu Qing, Meng, Lin, Shi, Jing Min
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2970966/
https://www.ncbi.nlm.nih.gov/pubmed/21578080
http://dx.doi.org/10.1107/S1600536809039920
Descripción
Sumario:In the title complex, [Cd(NCS)(2)(C(17)H(14)N(4))], the Cd(II) ion is in a distorted trigonal-bipyramidal CdN(5) coordination geometry. In the crystal structure, there is a π–π stacking inter­action involving a pyrazole ring and a symmetry-related pyridine ring with a centroid–centroid distance of 3.578 (3) Å.

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