[2-(3,5-Dimethyl-1H-pyrazol-1-yl-κN (2))-1,10-phenanthroline-κ(2) N,N′]bis­(thio­cyanato-κN)cadmium(II)

In the title complex, [Cd(NCS)(2)(C(17)H(14)N(4))], the Cd(II) ion is in a distorted trigonal-bipyramidal CdN(5) coordination geometry. In the crystal structure, there is a π–π stacking inter­action involving a pyrazole ring and a symmetry-related pyridine ring with a centroid–centroid distance of 3...

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Detalles Bibliográficos
Autores principales: Wang, Yu Qing, Meng, Lin, Shi, Jing Min
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2970966/
https://www.ncbi.nlm.nih.gov/pubmed/21578080
http://dx.doi.org/10.1107/S1600536809039920
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author Wang, Yu Qing
Meng, Lin
Shi, Jing Min
author_facet Wang, Yu Qing
Meng, Lin
Shi, Jing Min
author_sort Wang, Yu Qing
collection PubMed
description In the title complex, [Cd(NCS)(2)(C(17)H(14)N(4))], the Cd(II) ion is in a distorted trigonal-bipyramidal CdN(5) coordination geometry. In the crystal structure, there is a π–π stacking inter­action involving a pyrazole ring and a symmetry-related pyridine ring with a centroid–centroid distance of 3.578 (3) Å.
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spelling pubmed-29709662010-12-30 [2-(3,5-Dimethyl-1H-pyrazol-1-yl-κN (2))-1,10-phenanthroline-κ(2) N,N′]bis­(thio­cyanato-κN)cadmium(II) Wang, Yu Qing Meng, Lin Shi, Jing Min Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title complex, [Cd(NCS)(2)(C(17)H(14)N(4))], the Cd(II) ion is in a distorted trigonal-bipyramidal CdN(5) coordination geometry. In the crystal structure, there is a π–π stacking inter­action involving a pyrazole ring and a symmetry-related pyridine ring with a centroid–centroid distance of 3.578 (3) Å. International Union of Crystallography 2009-10-07 /pmc/articles/PMC2970966/ /pubmed/21578080 http://dx.doi.org/10.1107/S1600536809039920 Text en © Wang et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Wang, Yu Qing
Meng, Lin
Shi, Jing Min
[2-(3,5-Dimethyl-1H-pyrazol-1-yl-κN (2))-1,10-phenanthroline-κ(2) N,N′]bis­(thio­cyanato-κN)cadmium(II)
title [2-(3,5-Dimethyl-1H-pyrazol-1-yl-κN (2))-1,10-phenanthroline-κ(2) N,N′]bis­(thio­cyanato-κN)cadmium(II)
title_full [2-(3,5-Dimethyl-1H-pyrazol-1-yl-κN (2))-1,10-phenanthroline-κ(2) N,N′]bis­(thio­cyanato-κN)cadmium(II)
title_fullStr [2-(3,5-Dimethyl-1H-pyrazol-1-yl-κN (2))-1,10-phenanthroline-κ(2) N,N′]bis­(thio­cyanato-κN)cadmium(II)
title_full_unstemmed [2-(3,5-Dimethyl-1H-pyrazol-1-yl-κN (2))-1,10-phenanthroline-κ(2) N,N′]bis­(thio­cyanato-κN)cadmium(II)
title_short [2-(3,5-Dimethyl-1H-pyrazol-1-yl-κN (2))-1,10-phenanthroline-κ(2) N,N′]bis­(thio­cyanato-κN)cadmium(II)
title_sort [2-(3,5-dimethyl-1h-pyrazol-1-yl-κn (2))-1,10-phenanthroline-κ(2) n,n′]bis­(thio­cyanato-κn)cadmium(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2970966/
https://www.ncbi.nlm.nih.gov/pubmed/21578080
http://dx.doi.org/10.1107/S1600536809039920
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