(S)-3-[(S,E)-4-(4-Chloro­phen­yl)-1-nitro­but-3-en-2-yl]thian-4-one

The title compound, C(15)H(16)ClNO(3)S, was obtained by the organocatalytic asymmetric Michael addition of thian-4-one to 1-chloro-4-[(1E,3E)-4-nitro­buta-1,3-dien­yl]benzene. The double bond has an E configuration and the thian-4-one six-membered ring adopts a chair conformation. The crystal struct...

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Detalles Bibliográficos
Autores principales: Li, Zhaobo, Wang, Yifeng, Guo, Yi, Luo, Shuping
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2970967/
https://www.ncbi.nlm.nih.gov/pubmed/21578448
http://dx.doi.org/10.1107/S1600536809043608
Descripción
Sumario:The title compound, C(15)H(16)ClNO(3)S, was obtained by the organocatalytic asymmetric Michael addition of thian-4-one to 1-chloro-4-[(1E,3E)-4-nitro­buta-1,3-dien­yl]benzene. The double bond has an E configuration and the thian-4-one six-membered ring adopts a chair conformation. The crystal structure is stabilized by weak inter­molecular C—H⋯O hydrogen bonds.

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