(S)-3-[(S,E)-4-(4-Chloro­phen­yl)-1-nitro­but-3-en-2-yl]thian-4-one

The title compound, C(15)H(16)ClNO(3)S, was obtained by the organocatalytic asymmetric Michael addition of thian-4-one to 1-chloro-4-[(1E,3E)-4-nitro­buta-1,3-dien­yl]benzene. The double bond has an E configuration and the thian-4-one six-membered ring adopts a chair conformation. The crystal struct...

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Detalles Bibliográficos
Autores principales: Li, Zhaobo, Wang, Yifeng, Guo, Yi, Luo, Shuping
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2970967/
https://www.ncbi.nlm.nih.gov/pubmed/21578448
http://dx.doi.org/10.1107/S1600536809043608
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author Li, Zhaobo
Wang, Yifeng
Guo, Yi
Luo, Shuping
author_facet Li, Zhaobo
Wang, Yifeng
Guo, Yi
Luo, Shuping
author_sort Li, Zhaobo
collection PubMed
description The title compound, C(15)H(16)ClNO(3)S, was obtained by the organocatalytic asymmetric Michael addition of thian-4-one to 1-chloro-4-[(1E,3E)-4-nitro­buta-1,3-dien­yl]benzene. The double bond has an E configuration and the thian-4-one six-membered ring adopts a chair conformation. The crystal structure is stabilized by weak inter­molecular C—H⋯O hydrogen bonds.
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spelling pubmed-29709672010-12-30 (S)-3-[(S,E)-4-(4-Chloro­phen­yl)-1-nitro­but-3-en-2-yl]thian-4-one Li, Zhaobo Wang, Yifeng Guo, Yi Luo, Shuping Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(15)H(16)ClNO(3)S, was obtained by the organocatalytic asymmetric Michael addition of thian-4-one to 1-chloro-4-[(1E,3E)-4-nitro­buta-1,3-dien­yl]benzene. The double bond has an E configuration and the thian-4-one six-membered ring adopts a chair conformation. The crystal structure is stabilized by weak inter­molecular C—H⋯O hydrogen bonds. International Union of Crystallography 2009-10-28 /pmc/articles/PMC2970967/ /pubmed/21578448 http://dx.doi.org/10.1107/S1600536809043608 Text en © Li et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Li, Zhaobo
Wang, Yifeng
Guo, Yi
Luo, Shuping
(S)-3-[(S,E)-4-(4-Chloro­phen­yl)-1-nitro­but-3-en-2-yl]thian-4-one
title (S)-3-[(S,E)-4-(4-Chloro­phen­yl)-1-nitro­but-3-en-2-yl]thian-4-one
title_full (S)-3-[(S,E)-4-(4-Chloro­phen­yl)-1-nitro­but-3-en-2-yl]thian-4-one
title_fullStr (S)-3-[(S,E)-4-(4-Chloro­phen­yl)-1-nitro­but-3-en-2-yl]thian-4-one
title_full_unstemmed (S)-3-[(S,E)-4-(4-Chloro­phen­yl)-1-nitro­but-3-en-2-yl]thian-4-one
title_short (S)-3-[(S,E)-4-(4-Chloro­phen­yl)-1-nitro­but-3-en-2-yl]thian-4-one
title_sort (s)-3-[(s,e)-4-(4-chloro­phen­yl)-1-nitro­but-3-en-2-yl]thian-4-one
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2970967/
https://www.ncbi.nlm.nih.gov/pubmed/21578448
http://dx.doi.org/10.1107/S1600536809043608
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AT wangyifeng s3se44chlorophenyl1nitrobut3en2ylthian4one
AT guoyi s3se44chlorophenyl1nitrobut3en2ylthian4one
AT luoshuping s3se44chlorophenyl1nitrobut3en2ylthian4one

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