Hexaaqua­magnesium(II) bis­[4-(3-pyrid­yl)pyrimidine-2-sulfonate] tetra­hydrate

The asymmetric unit of the title compound, [Mg(H(2)O)(6)](C(9)H(6)N(3)O(3)S)(2)·4H(2)O, contains half of a centrosymmetric cation, one 4-(3-pyrid­yl)pyrimidin-2-sulfonate anion and two solvent water mol­ecules. Inter­molecular O—H⋯O and O—H⋯N hydrogen bonds link the cations, anions and water mol­ecu...

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Detalles Bibliográficos
Autores principales: Wang, Yan-Ping, Li, Jian, Dong, Hua-Ze
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2970970/
https://www.ncbi.nlm.nih.gov/pubmed/21578168
http://dx.doi.org/10.1107/S160053680904344X
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author Wang, Yan-Ping
Li, Jian
Dong, Hua-Ze
author_facet Wang, Yan-Ping
Li, Jian
Dong, Hua-Ze
author_sort Wang, Yan-Ping
collection PubMed
description The asymmetric unit of the title compound, [Mg(H(2)O)(6)](C(9)H(6)N(3)O(3)S)(2)·4H(2)O, contains half of a centrosymmetric cation, one 4-(3-pyrid­yl)pyrimidin-2-sulfonate anion and two solvent water mol­ecules. Inter­molecular O—H⋯O and O—H⋯N hydrogen bonds link the cations, anions and water mol­ecules into a three-dimensional supra­molecular structure. The crystal packing also exhibits inter­molecular π–π inter­actions between the aromatic rings of the anions with a centroid–centroid distance of 3.604 (2) Å.
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spelling pubmed-29709702010-12-30 Hexaaqua­magnesium(II) bis­[4-(3-pyrid­yl)pyrimidine-2-sulfonate] tetra­hydrate Wang, Yan-Ping Li, Jian Dong, Hua-Ze Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The asymmetric unit of the title compound, [Mg(H(2)O)(6)](C(9)H(6)N(3)O(3)S)(2)·4H(2)O, contains half of a centrosymmetric cation, one 4-(3-pyrid­yl)pyrimidin-2-sulfonate anion and two solvent water mol­ecules. Inter­molecular O—H⋯O and O—H⋯N hydrogen bonds link the cations, anions and water mol­ecules into a three-dimensional supra­molecular structure. The crystal packing also exhibits inter­molecular π–π inter­actions between the aromatic rings of the anions with a centroid–centroid distance of 3.604 (2) Å. International Union of Crystallography 2009-10-28 /pmc/articles/PMC2970970/ /pubmed/21578168 http://dx.doi.org/10.1107/S160053680904344X Text en © Wang et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Wang, Yan-Ping
Li, Jian
Dong, Hua-Ze
Hexaaqua­magnesium(II) bis­[4-(3-pyrid­yl)pyrimidine-2-sulfonate] tetra­hydrate
title Hexaaqua­magnesium(II) bis­[4-(3-pyrid­yl)pyrimidine-2-sulfonate] tetra­hydrate
title_full Hexaaqua­magnesium(II) bis­[4-(3-pyrid­yl)pyrimidine-2-sulfonate] tetra­hydrate
title_fullStr Hexaaqua­magnesium(II) bis­[4-(3-pyrid­yl)pyrimidine-2-sulfonate] tetra­hydrate
title_full_unstemmed Hexaaqua­magnesium(II) bis­[4-(3-pyrid­yl)pyrimidine-2-sulfonate] tetra­hydrate
title_short Hexaaqua­magnesium(II) bis­[4-(3-pyrid­yl)pyrimidine-2-sulfonate] tetra­hydrate
title_sort hexaaqua­magnesium(ii) bis­[4-(3-pyrid­yl)pyrimidine-2-sulfonate] tetra­hydrate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2970970/
https://www.ncbi.nlm.nih.gov/pubmed/21578168
http://dx.doi.org/10.1107/S160053680904344X
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