catena-Poly[[silver(I)-μ-dipyrazin-2-ylamine] perchlorate monohydrate]

In the title complex, {[Ag(C(8)H(7)N(5))]ClO(4)·H(2)O}(n), the multidentate dipyrazin-2-ylamine acts as a μ(2)-bridging link with an anti–syn configuration, assembling the Ag(I) ions into a zigzag chain structure. The Ag(I) ion is linearly coordinated by two dipyrazin-2-ylamine ligands through two p...

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Detalles Bibliográficos
Autores principales: Song, Wei Feng, Wan, Chong-Qing, Liu, Jianfeng
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2970971/
https://www.ncbi.nlm.nih.gov/pubmed/21578095
http://dx.doi.org/10.1107/S1600536809037532
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author Song, Wei Feng
Wan, Chong-Qing
Liu, Jianfeng
author_facet Song, Wei Feng
Wan, Chong-Qing
Liu, Jianfeng
author_sort Song, Wei Feng
collection PubMed
description In the title complex, {[Ag(C(8)H(7)N(5))]ClO(4)·H(2)O}(n), the multidentate dipyrazin-2-ylamine acts as a μ(2)-bridging link with an anti–syn configuration, assembling the Ag(I) ions into a zigzag chain structure. The Ag(I) ion is linearly coordinated by two dipyrazin-2-ylamine ligands through two pyrazine N atoms. (ClO(4) (−))⋯π(pyrazine) [O⋯centroid distances of 3.612 (3) and 3.664 (1) Å] and π–π inter­actions [centroid–centroid distance = 3.518 (2) Å] as well as O—H⋯O and N—H⋯O hydrogen-bonds assemble the chains into a three-dimensional supra­molecular aggregation.
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spelling pubmed-29709712010-12-30 catena-Poly[[silver(I)-μ-dipyrazin-2-ylamine] perchlorate monohydrate] Song, Wei Feng Wan, Chong-Qing Liu, Jianfeng Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title complex, {[Ag(C(8)H(7)N(5))]ClO(4)·H(2)O}(n), the multidentate dipyrazin-2-ylamine acts as a μ(2)-bridging link with an anti–syn configuration, assembling the Ag(I) ions into a zigzag chain structure. The Ag(I) ion is linearly coordinated by two dipyrazin-2-ylamine ligands through two pyrazine N atoms. (ClO(4) (−))⋯π(pyrazine) [O⋯centroid distances of 3.612 (3) and 3.664 (1) Å] and π–π inter­actions [centroid–centroid distance = 3.518 (2) Å] as well as O—H⋯O and N—H⋯O hydrogen-bonds assemble the chains into a three-dimensional supra­molecular aggregation. International Union of Crystallography 2009-10-10 /pmc/articles/PMC2970971/ /pubmed/21578095 http://dx.doi.org/10.1107/S1600536809037532 Text en © Song et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Song, Wei Feng
Wan, Chong-Qing
Liu, Jianfeng
catena-Poly[[silver(I)-μ-dipyrazin-2-ylamine] perchlorate monohydrate]
title catena-Poly[[silver(I)-μ-dipyrazin-2-ylamine] perchlorate monohydrate]
title_full catena-Poly[[silver(I)-μ-dipyrazin-2-ylamine] perchlorate monohydrate]
title_fullStr catena-Poly[[silver(I)-μ-dipyrazin-2-ylamine] perchlorate monohydrate]
title_full_unstemmed catena-Poly[[silver(I)-μ-dipyrazin-2-ylamine] perchlorate monohydrate]
title_short catena-Poly[[silver(I)-μ-dipyrazin-2-ylamine] perchlorate monohydrate]
title_sort catena-poly[[silver(i)-μ-dipyrazin-2-ylamine] perchlorate monohydrate]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2970971/
https://www.ncbi.nlm.nih.gov/pubmed/21578095
http://dx.doi.org/10.1107/S1600536809037532
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