(3E,5E)-1-Benzyl-3,5-bis­(2-fluoro­benzyl­idene)piperidin-4-one

The inversion-related mol­ecules of the title compound, C(26)H(21)F(2)NO, associate into closed dimeric subunits via co-operative C—H⋯π inter­actions. Two non-classical C—H⋯O and one C—H⋯N intra­molecular hydrogen bonds are also found in the crystal structure. The piperidin-4-one ring adopts a sofa...

Descripción completa

Detalles Bibliográficos
Autores principales: Rathore, R. S., Karthikeyan, N. S., Sathiyanarayanan, K., Aravindan, P. G.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2970975/
https://www.ncbi.nlm.nih.gov/pubmed/21578277
http://dx.doi.org/10.1107/S1600536809039609
Descripción
Sumario:The inversion-related mol­ecules of the title compound, C(26)H(21)F(2)NO, associate into closed dimeric subunits via co-operative C—H⋯π inter­actions. Two non-classical C—H⋯O and one C—H⋯N intra­molecular hydrogen bonds are also found in the crystal structure. The piperidin-4-one ring adopts a sofa conforamtion with the 1-benzyl group in the equatorial position, and the equiplanar fluoro­phenyl substituents in the 3- and 5-positions stretched out on either side. The 1-benzyl group is disposed towards the substituent in the 6th position of the piperidin-4-one ring. The 3,5-diene units possess E configurations.

Ejemplares similares