5-(4,5-Diiodo-1,3-dithiol-2-yl­idene)-4′,5′-bis­(methyl­sulfan­yl)-2,2′-bi-1,3-dithiole-4(5H)-thione

The mol­ecular skeleton of the title mol­ecule, C(11)H(6)I(2)S(9), is nearly planar [maximum deviation 0.052 (3) Å] except for the two methyl groups. In the crystal, mol­ecules related by translation along b axis are associated into columns through π–π inter­actions between the five-membered rings,...

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Detalles Bibliográficos
Autores principales: Ueda, Kazumasa, Yoza, Kenji
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2970979/
https://www.ncbi.nlm.nih.gov/pubmed/21578421
http://dx.doi.org/10.1107/S1600536809042573
Descripción
Sumario:The mol­ecular skeleton of the title mol­ecule, C(11)H(6)I(2)S(9), is nearly planar [maximum deviation 0.052 (3) Å] except for the two methyl groups. In the crystal, mol­ecules related by translation along b axis are associated into columns through π–π inter­actions between the five-membered rings, with a centroid–centroid distance of 3.593 (5) Å. Inter­action between adjacent columns is accomplished by short S⋯I contacts of 3.2099 (4) Å.

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