5-(4,5-Diiodo-1,3-dithiol-2-yl­idene)-4′,5′-bis­(methyl­sulfan­yl)-2,2′-bi-1,3-dithiole-4(5H)-thione

The mol­ecular skeleton of the title mol­ecule, C(11)H(6)I(2)S(9), is nearly planar [maximum deviation 0.052 (3) Å] except for the two methyl groups. In the crystal, mol­ecules related by translation along b axis are associated into columns through π–π inter­actions between the five-membered rings,...

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Detalles Bibliográficos
Autores principales: Ueda, Kazumasa, Yoza, Kenji
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2970979/
https://www.ncbi.nlm.nih.gov/pubmed/21578421
http://dx.doi.org/10.1107/S1600536809042573
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author Ueda, Kazumasa
Yoza, Kenji
author_facet Ueda, Kazumasa
Yoza, Kenji
author_sort Ueda, Kazumasa
collection PubMed
description The mol­ecular skeleton of the title mol­ecule, C(11)H(6)I(2)S(9), is nearly planar [maximum deviation 0.052 (3) Å] except for the two methyl groups. In the crystal, mol­ecules related by translation along b axis are associated into columns through π–π inter­actions between the five-membered rings, with a centroid–centroid distance of 3.593 (5) Å. Inter­action between adjacent columns is accomplished by short S⋯I contacts of 3.2099 (4) Å.
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spelling pubmed-29709792010-12-30 5-(4,5-Diiodo-1,3-dithiol-2-yl­idene)-4′,5′-bis­(methyl­sulfan­yl)-2,2′-bi-1,3-dithiole-4(5H)-thione Ueda, Kazumasa Yoza, Kenji Acta Crystallogr Sect E Struct Rep Online Organic Papers The mol­ecular skeleton of the title mol­ecule, C(11)H(6)I(2)S(9), is nearly planar [maximum deviation 0.052 (3) Å] except for the two methyl groups. In the crystal, mol­ecules related by translation along b axis are associated into columns through π–π inter­actions between the five-membered rings, with a centroid–centroid distance of 3.593 (5) Å. Inter­action between adjacent columns is accomplished by short S⋯I contacts of 3.2099 (4) Å. International Union of Crystallography 2009-10-23 /pmc/articles/PMC2970979/ /pubmed/21578421 http://dx.doi.org/10.1107/S1600536809042573 Text en © Ueda and Yoza 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Ueda, Kazumasa
Yoza, Kenji
5-(4,5-Diiodo-1,3-dithiol-2-yl­idene)-4′,5′-bis­(methyl­sulfan­yl)-2,2′-bi-1,3-dithiole-4(5H)-thione
title 5-(4,5-Diiodo-1,3-dithiol-2-yl­idene)-4′,5′-bis­(methyl­sulfan­yl)-2,2′-bi-1,3-dithiole-4(5H)-thione
title_full 5-(4,5-Diiodo-1,3-dithiol-2-yl­idene)-4′,5′-bis­(methyl­sulfan­yl)-2,2′-bi-1,3-dithiole-4(5H)-thione
title_fullStr 5-(4,5-Diiodo-1,3-dithiol-2-yl­idene)-4′,5′-bis­(methyl­sulfan­yl)-2,2′-bi-1,3-dithiole-4(5H)-thione
title_full_unstemmed 5-(4,5-Diiodo-1,3-dithiol-2-yl­idene)-4′,5′-bis­(methyl­sulfan­yl)-2,2′-bi-1,3-dithiole-4(5H)-thione
title_short 5-(4,5-Diiodo-1,3-dithiol-2-yl­idene)-4′,5′-bis­(methyl­sulfan­yl)-2,2′-bi-1,3-dithiole-4(5H)-thione
title_sort 5-(4,5-diiodo-1,3-dithiol-2-yl­idene)-4′,5′-bis­(methyl­sulfan­yl)-2,2′-bi-1,3-dithiole-4(5h)-thione
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2970979/
https://www.ncbi.nlm.nih.gov/pubmed/21578421
http://dx.doi.org/10.1107/S1600536809042573
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AT yozakenji 545diiodo13dithiol2ylidene45bismethylsulfanyl22bi13dithiole45hthione

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