Cargando…
Diethyl 6,13-dioxo-5,7,12,13b,13c,14-hexahydro-6H,13H-5a,6a,12a,13a-tetraazabenz[5,6]azuleno[2,1,8-ija]benz[f]azulene-13b,13c-dicarboxylate 1,2-dichloroethane solvate
In the title inclusion compound, C(26)H(26)N(4)O(6)·C(2)H(4)Cl(2), the solvent molecule occupies a cavity inside the clip-type molecule which is based on the glycoluril skeleton with two ethyl acetate substituents on the convex face of the glycoluril system. The dihedral angle between the aromatic...
Autores principales: | , |
---|---|
Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2009
|
Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2970980/ https://www.ncbi.nlm.nih.gov/pubmed/21578341 http://dx.doi.org/10.1107/S1600536809041373 |
Sumario: | In the title inclusion compound, C(26)H(26)N(4)O(6)·C(2)H(4)Cl(2), the solvent molecule occupies a cavity inside the clip-type molecule which is based on the glycoluril skeleton with two ethyl acetate substituents on the convex face of the glycoluril system. The dihedral angle between the aromatic rings of the host is 43.59 (4)° and the centroid–centroid distance is 6.741 (5) Å. The 1,2-dichloroetane molecule adopts a gauche conformation enabling it to participate in C—H⋯π interactions with the host. The packing motif in the title compound differs from that observed in the crystal structures of the host and in the benzene solvate. The host molecules are linked into tapes by π–π stacking interactions (centroid–centroid distance = 3.733 Å) and are further assembled into layers via C—H⋯O interactions. One of the ethyl groups is disorded over two positions with site-occupancy factors of 0.702 (14) and 0.298 (14). |
---|