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Ethylenediammonium dichloroiodide chloride
The asymmetric unit of the crystal structure of the title compound, C(2)H(10)N(2) (2+)·Cl(2)I(−)·Cl(−), contains two ethylenediammonium cations, two [ICl(2)](−) anions and two Cl(−) anions, of which one cation, one [ICl(2)](−) anion and one Cl(−) anion have site symmetry 2, with the mid-point of t...
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| Formato: | Texto |
| Lenguaje: | English |
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International Union of Crystallography
2009
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2970981/ https://www.ncbi.nlm.nih.gov/pubmed/21578241 http://dx.doi.org/10.1107/S1600536809039038 |
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| author | Chen, Li-Zhuang |
| author_facet | Chen, Li-Zhuang |
| author_sort | Chen, Li-Zhuang |
| collection | PubMed |
| description | The asymmetric unit of the crystal structure of the title compound, C(2)H(10)N(2) (2+)·Cl(2)I(−)·Cl(−), contains two ethylenediammonium cations, two [ICl(2)](−) anions and two Cl(−) anions, of which one cation, one [ICl(2)](−) anion and one Cl(−) anion have site symmetry 2, with the mid-point of the C—C bond of the cation, the I atom of [ICl(2)](−) anion and the Cl(−) anion located on the twofold rotation axes. The two independent cations show different conformations, the N—C—C—N torsion angles being 160.1 (2) and −73.1 (4)°. The crystal structure is stabilized by extensive intermolecular N—H⋯Cl hydrogen bonding. |
| format | Text |
| id | pubmed-2970981 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2009 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-29709812010-12-30 Ethylenediammonium dichloroiodide chloride Chen, Li-Zhuang Acta Crystallogr Sect E Struct Rep Online Organic Papers The asymmetric unit of the crystal structure of the title compound, C(2)H(10)N(2) (2+)·Cl(2)I(−)·Cl(−), contains two ethylenediammonium cations, two [ICl(2)](−) anions and two Cl(−) anions, of which one cation, one [ICl(2)](−) anion and one Cl(−) anion have site symmetry 2, with the mid-point of the C—C bond of the cation, the I atom of [ICl(2)](−) anion and the Cl(−) anion located on the twofold rotation axes. The two independent cations show different conformations, the N—C—C—N torsion angles being 160.1 (2) and −73.1 (4)°. The crystal structure is stabilized by extensive intermolecular N—H⋯Cl hydrogen bonding. International Union of Crystallography 2009-10-03 /pmc/articles/PMC2970981/ /pubmed/21578241 http://dx.doi.org/10.1107/S1600536809039038 Text en © Li-Zhuang Chen 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Organic Papers Chen, Li-Zhuang Ethylenediammonium dichloroiodide chloride |
| title | Ethylenediammonium dichloroiodide chloride |
| title_full | Ethylenediammonium dichloroiodide chloride |
| title_fullStr | Ethylenediammonium dichloroiodide chloride |
| title_full_unstemmed | Ethylenediammonium dichloroiodide chloride |
| title_short | Ethylenediammonium dichloroiodide chloride |
| title_sort | ethylenediammonium dichloroiodide chloride |
| topic | Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2970981/ https://www.ncbi.nlm.nih.gov/pubmed/21578241 http://dx.doi.org/10.1107/S1600536809039038 |
| work_keys_str_mv | AT chenlizhuang ethylenediammoniumdichloroiodidechloride |