(Z)-Isobutyl 2-benzamido-3-(4-chloro­phen­yl)acrylate

The title compound, C(20)H(20)ClNO(3), is a α-amino acid derivative which displays a Z configuration about the C=C double bond. The dihedral angle betwen the aromatic rings is 87.75 (12)°. The mol­ecular conformation is stabilized by an intra­molecular C—H⋯N hydrogen bond. In the crystal structure,...

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Detalles Bibliográficos
Autores principales: Su, Gui-Fa, Wang, Zhong-Chang, Huang, Wan-Yun, Wang, Zhi-Xin, Chen, Zi-Lu
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2970985/
https://www.ncbi.nlm.nih.gov/pubmed/21578473
http://dx.doi.org/10.1107/S1600536809043931
Descripción
Sumario:The title compound, C(20)H(20)ClNO(3), is a α-amino acid derivative which displays a Z configuration about the C=C double bond. The dihedral angle betwen the aromatic rings is 87.75 (12)°. The mol­ecular conformation is stabilized by an intra­molecular C—H⋯N hydrogen bond. In the crystal structure, centrosymmetrically related mol­ecules inter­act through inter­molecular C—H⋯O hydrogen-bond inter­actions, forming dimers. The dimers are further linked into chains parallel to the a axis by N—H⋯O hydrogen bonds. The methyl groups of the isopropyl group are disordered over two positions with occupancy factors of 0.5.

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