(Z)-Isobutyl 2-benzamido-3-(4-chloro­phen­yl)acrylate

The title compound, C(20)H(20)ClNO(3), is a α-amino acid derivative which displays a Z configuration about the C=C double bond. The dihedral angle betwen the aromatic rings is 87.75 (12)°. The mol­ecular conformation is stabilized by an intra­molecular C—H⋯N hydrogen bond. In the crystal structure,...

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Detalles Bibliográficos
Autores principales: Su, Gui-Fa, Wang, Zhong-Chang, Huang, Wan-Yun, Wang, Zhi-Xin, Chen, Zi-Lu
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2970985/
https://www.ncbi.nlm.nih.gov/pubmed/21578473
http://dx.doi.org/10.1107/S1600536809043931
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author Su, Gui-Fa
Wang, Zhong-Chang
Huang, Wan-Yun
Wang, Zhi-Xin
Chen, Zi-Lu
author_facet Su, Gui-Fa
Wang, Zhong-Chang
Huang, Wan-Yun
Wang, Zhi-Xin
Chen, Zi-Lu
author_sort Su, Gui-Fa
collection PubMed
description The title compound, C(20)H(20)ClNO(3), is a α-amino acid derivative which displays a Z configuration about the C=C double bond. The dihedral angle betwen the aromatic rings is 87.75 (12)°. The mol­ecular conformation is stabilized by an intra­molecular C—H⋯N hydrogen bond. In the crystal structure, centrosymmetrically related mol­ecules inter­act through inter­molecular C—H⋯O hydrogen-bond inter­actions, forming dimers. The dimers are further linked into chains parallel to the a axis by N—H⋯O hydrogen bonds. The methyl groups of the isopropyl group are disordered over two positions with occupancy factors of 0.5.
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spelling pubmed-29709852010-12-30 (Z)-Isobutyl 2-benzamido-3-(4-chloro­phen­yl)acrylate Su, Gui-Fa Wang, Zhong-Chang Huang, Wan-Yun Wang, Zhi-Xin Chen, Zi-Lu Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(20)H(20)ClNO(3), is a α-amino acid derivative which displays a Z configuration about the C=C double bond. The dihedral angle betwen the aromatic rings is 87.75 (12)°. The mol­ecular conformation is stabilized by an intra­molecular C—H⋯N hydrogen bond. In the crystal structure, centrosymmetrically related mol­ecules inter­act through inter­molecular C—H⋯O hydrogen-bond inter­actions, forming dimers. The dimers are further linked into chains parallel to the a axis by N—H⋯O hydrogen bonds. The methyl groups of the isopropyl group are disordered over two positions with occupancy factors of 0.5. International Union of Crystallography 2009-10-28 /pmc/articles/PMC2970985/ /pubmed/21578473 http://dx.doi.org/10.1107/S1600536809043931 Text en © Su et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Su, Gui-Fa
Wang, Zhong-Chang
Huang, Wan-Yun
Wang, Zhi-Xin
Chen, Zi-Lu
(Z)-Isobutyl 2-benzamido-3-(4-chloro­phen­yl)acrylate
title (Z)-Isobutyl 2-benzamido-3-(4-chloro­phen­yl)acrylate
title_full (Z)-Isobutyl 2-benzamido-3-(4-chloro­phen­yl)acrylate
title_fullStr (Z)-Isobutyl 2-benzamido-3-(4-chloro­phen­yl)acrylate
title_full_unstemmed (Z)-Isobutyl 2-benzamido-3-(4-chloro­phen­yl)acrylate
title_short (Z)-Isobutyl 2-benzamido-3-(4-chloro­phen­yl)acrylate
title_sort (z)-isobutyl 2-benzamido-3-(4-chloro­phen­yl)acrylate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2970985/
https://www.ncbi.nlm.nih.gov/pubmed/21578473
http://dx.doi.org/10.1107/S1600536809043931
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