Chloridotetra­kis(pyridine-4-carb­alde­hyde-κN)copper(II) chloride

In the mol­ecular structure of the title compound, [CuCl(C(6)H(5)NO)(4)]Cl, the Cu(II) atom is coordinated by four N atoms of four pyridine-4-carboxaldehyde ligands and one chloride anion in a slightly distorted square-pyramidal coordination geometry. There is also a non-coordinating Cl(−) anion in...

Descripción completa

Detalles Bibliográficos
Autores principales: Meng, Xiu-Jin, Zhang, Shu-Hua, Yang, Ge-Ge, Huang, Xue-Ren, Jiang, Yi-Min
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2970991/
https://www.ncbi.nlm.nih.gov/pubmed/21578129
http://dx.doi.org/10.1107/S1600536809041816
_version_ 1782190520199544832
author Meng, Xiu-Jin
Zhang, Shu-Hua
Yang, Ge-Ge
Huang, Xue-Ren
Jiang, Yi-Min
author_facet Meng, Xiu-Jin
Zhang, Shu-Hua
Yang, Ge-Ge
Huang, Xue-Ren
Jiang, Yi-Min
author_sort Meng, Xiu-Jin
collection PubMed
description In the mol­ecular structure of the title compound, [CuCl(C(6)H(5)NO)(4)]Cl, the Cu(II) atom is coordinated by four N atoms of four pyridine-4-carboxaldehyde ligands and one chloride anion in a slightly distorted square-pyramidal coordination geometry. There is also a non-coordinating Cl(−) anion in the crystal structure. The Cu(II) atom and both Cl atoms are situated on fourfold rotation axes. A weak C—H⋯Cl inter­action is also present.
format Text
id pubmed-2970991
institution National Center for Biotechnology Information
language English
publishDate 2009
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-29709912010-12-30 Chloridotetra­kis(pyridine-4-carb­alde­hyde-κN)copper(II) chloride Meng, Xiu-Jin Zhang, Shu-Hua Yang, Ge-Ge Huang, Xue-Ren Jiang, Yi-Min Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the mol­ecular structure of the title compound, [CuCl(C(6)H(5)NO)(4)]Cl, the Cu(II) atom is coordinated by four N atoms of four pyridine-4-carboxaldehyde ligands and one chloride anion in a slightly distorted square-pyramidal coordination geometry. There is also a non-coordinating Cl(−) anion in the crystal structure. The Cu(II) atom and both Cl atoms are situated on fourfold rotation axes. A weak C—H⋯Cl inter­action is also present. International Union of Crystallography 2009-10-17 /pmc/articles/PMC2970991/ /pubmed/21578129 http://dx.doi.org/10.1107/S1600536809041816 Text en © Meng et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Meng, Xiu-Jin
Zhang, Shu-Hua
Yang, Ge-Ge
Huang, Xue-Ren
Jiang, Yi-Min
Chloridotetra­kis(pyridine-4-carb­alde­hyde-κN)copper(II) chloride
title Chloridotetra­kis(pyridine-4-carb­alde­hyde-κN)copper(II) chloride
title_full Chloridotetra­kis(pyridine-4-carb­alde­hyde-κN)copper(II) chloride
title_fullStr Chloridotetra­kis(pyridine-4-carb­alde­hyde-κN)copper(II) chloride
title_full_unstemmed Chloridotetra­kis(pyridine-4-carb­alde­hyde-κN)copper(II) chloride
title_short Chloridotetra­kis(pyridine-4-carb­alde­hyde-κN)copper(II) chloride
title_sort chloridotetra­kis(pyridine-4-carb­alde­hyde-κn)copper(ii) chloride
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2970991/
https://www.ncbi.nlm.nih.gov/pubmed/21578129
http://dx.doi.org/10.1107/S1600536809041816
work_keys_str_mv AT mengxiujin chloridotetrakispyridine4carbaldehydekncopperiichloride
AT zhangshuhua chloridotetrakispyridine4carbaldehydekncopperiichloride
AT yanggege chloridotetrakispyridine4carbaldehydekncopperiichloride
AT huangxueren chloridotetrakispyridine4carbaldehydekncopperiichloride
AT jiangyimin chloridotetrakispyridine4carbaldehydekncopperiichloride

Ejemplares similares