Poly[bis(phenethyl­ammonium) [di­bromido­plumbate(II)]-di-μ-bromido]]

Crystals of the title compound, {(C(6)H(5)C(2)H(4)NH(3))(2)[PbBr(4)]}(n), were grown at room temperature from a solution in N,N-dimethyl­formamide (DMF) using nitro­methane as the poor solvent. This perovskite-type organic–inorganic hybrid compound consists of well ordered sheets of corner-sharing d...

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Detalles Bibliográficos
Autores principales: Shibuya, Kengo, Koshimizu, Masanori, Nishikido, Fumihiko, Saito, Haruo, Kishimoto, Shunji
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2970995/
https://www.ncbi.nlm.nih.gov/pubmed/21578085
http://dx.doi.org/10.1107/S160053680903712X
Descripción
Sumario:Crystals of the title compound, {(C(6)H(5)C(2)H(4)NH(3))(2)[PbBr(4)]}(n), were grown at room temperature from a solution in N,N-dimethyl­formamide (DMF) using nitro­methane as the poor solvent. This perovskite-type organic–inorganic hybrid compound consists of well ordered sheets of corner-sharing disordered PbBr(6) octa­hedra separated by bilayers of phenethyl­ammonium cations. The octa­hedra are rotated and tilted due to N—H⋯Br hydrogen bonds with the ammonium groups, generating a superstructure in the unit cell similar to that of the tetra­chloridoplumbate (C(6)H(5)C(2)H(4)NH(3))(2)[PbCl(4)].

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