Poly[bis(phenethyl­ammonium) [di­bromido­plumbate(II)]-di-μ-bromido]]

Crystals of the title compound, {(C(6)H(5)C(2)H(4)NH(3))(2)[PbBr(4)]}(n), were grown at room temperature from a solution in N,N-dimethyl­formamide (DMF) using nitro­methane as the poor solvent. This perovskite-type organic–inorganic hybrid compound consists of well ordered sheets of corner-sharing d...

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Autores principales: Shibuya, Kengo, Koshimizu, Masanori, Nishikido, Fumihiko, Saito, Haruo, Kishimoto, Shunji
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2970995/
https://www.ncbi.nlm.nih.gov/pubmed/21578085
http://dx.doi.org/10.1107/S160053680903712X
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author Shibuya, Kengo
Koshimizu, Masanori
Nishikido, Fumihiko
Saito, Haruo
Kishimoto, Shunji
author_facet Shibuya, Kengo
Koshimizu, Masanori
Nishikido, Fumihiko
Saito, Haruo
Kishimoto, Shunji
author_sort Shibuya, Kengo
collection PubMed
description Crystals of the title compound, {(C(6)H(5)C(2)H(4)NH(3))(2)[PbBr(4)]}(n), were grown at room temperature from a solution in N,N-dimethyl­formamide (DMF) using nitro­methane as the poor solvent. This perovskite-type organic–inorganic hybrid compound consists of well ordered sheets of corner-sharing disordered PbBr(6) octa­hedra separated by bilayers of phenethyl­ammonium cations. The octa­hedra are rotated and tilted due to N—H⋯Br hydrogen bonds with the ammonium groups, generating a superstructure in the unit cell similar to that of the tetra­chloridoplumbate (C(6)H(5)C(2)H(4)NH(3))(2)[PbCl(4)].
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spelling pubmed-29709952010-12-30 Poly[bis(phenethyl­ammonium) [di­bromido­plumbate(II)]-di-μ-bromido]] Shibuya, Kengo Koshimizu, Masanori Nishikido, Fumihiko Saito, Haruo Kishimoto, Shunji Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers Crystals of the title compound, {(C(6)H(5)C(2)H(4)NH(3))(2)[PbBr(4)]}(n), were grown at room temperature from a solution in N,N-dimethyl­formamide (DMF) using nitro­methane as the poor solvent. This perovskite-type organic–inorganic hybrid compound consists of well ordered sheets of corner-sharing disordered PbBr(6) octa­hedra separated by bilayers of phenethyl­ammonium cations. The octa­hedra are rotated and tilted due to N—H⋯Br hydrogen bonds with the ammonium groups, generating a superstructure in the unit cell similar to that of the tetra­chloridoplumbate (C(6)H(5)C(2)H(4)NH(3))(2)[PbCl(4)]. International Union of Crystallography 2009-10-07 /pmc/articles/PMC2970995/ /pubmed/21578085 http://dx.doi.org/10.1107/S160053680903712X Text en © Shibuya et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Shibuya, Kengo
Koshimizu, Masanori
Nishikido, Fumihiko
Saito, Haruo
Kishimoto, Shunji
Poly[bis(phenethyl­ammonium) [di­bromido­plumbate(II)]-di-μ-bromido]]
title Poly[bis(phenethyl­ammonium) [di­bromido­plumbate(II)]-di-μ-bromido]]
title_full Poly[bis(phenethyl­ammonium) [di­bromido­plumbate(II)]-di-μ-bromido]]
title_fullStr Poly[bis(phenethyl­ammonium) [di­bromido­plumbate(II)]-di-μ-bromido]]
title_full_unstemmed Poly[bis(phenethyl­ammonium) [di­bromido­plumbate(II)]-di-μ-bromido]]
title_short Poly[bis(phenethyl­ammonium) [di­bromido­plumbate(II)]-di-μ-bromido]]
title_sort poly[bis(phenethyl­ammonium) [di­bromido­plumbate(ii)]-di-μ-bromido]]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2970995/
https://www.ncbi.nlm.nih.gov/pubmed/21578085
http://dx.doi.org/10.1107/S160053680903712X
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AT nishikidofumihiko polybisphenethylammoniumdibromidoplumbateiidimbromido
AT saitoharuo polybisphenethylammoniumdibromidoplumbateiidimbromido
AT kishimotoshunji polybisphenethylammoniumdibromidoplumbateiidimbromido

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