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A redetermination of (2-methoxyphenyl)diphenylphosphine
The asymmetric unit of the title triphenylphosphine compound, C(19)H(17)OP, consists of two crystallographically independent molecules with similar conformations. One of these two molecules has a whole-molecule disorder over two positions with refined occupancies of 0.753 (3) and 0.247 (3). The...
Autores principales: | , , , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2009
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2970997/ https://www.ncbi.nlm.nih.gov/pubmed/21578272 http://dx.doi.org/10.1107/S1600536809038835 |
Sumario: | The asymmetric unit of the title triphenylphosphine compound, C(19)H(17)OP, consists of two crystallographically independent molecules with similar conformations. One of these two molecules has a whole-molecule disorder over two positions with refined occupancies of 0.753 (3) and 0.247 (3). The dihedral angles between the three benzene rings are 89.69 (7), 76.54 (7) and 86.02 (7)° in the non-disordered molecule and the corresponding angles are 88.3 (4), 83.2 (4) and 84.2 (3)° for the major component and 80.2 (11), 89.5 (11) and 74.4 (9)° for the minor component of the disordered molecule. This structure has been reported previously [Suomalainen et al. (2000 ▶). Eur. J. Inorg. Chem. pp. 2607–2613]; however, the disorder detailed here was not mentioned in that determination. In the crystal structure, the molecules are stacked down the b axis and stabilized by C—H⋯π interactions. |
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