Di-μ(2)-chlorido-bis­[chlorido(η(6)-hexa­methyl­benzene)ruthenium(II)]

Dimeric mol­ecules of the title compound, [Ru(2)Cl(4)(C(12)H(18))(2)], are located on a crystallographic centre of inversion with one mol­ecule in the asymmetric unit. The hexa­methyl­benzene rings are in an η(6)-coordination to the ruthenium centres, which are bridged by two chloride ligands. In ad...

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Detalles Bibliográficos
Autores principales: González-Torres, Yunuem, Espinosa-Jalapa, Noel, Hernández-Ortega, Simón, Le Lagadec, Ronan, Morales-Morales, David
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971002/
https://www.ncbi.nlm.nih.gov/pubmed/21578121
http://dx.doi.org/10.1107/S1600536809041154
Descripción
Sumario:Dimeric mol­ecules of the title compound, [Ru(2)Cl(4)(C(12)H(18))(2)], are located on a crystallographic centre of inversion with one mol­ecule in the asymmetric unit. The hexa­methyl­benzene rings are in an η(6)-coordination to the ruthenium centres, which are bridged by two chloride ligands. In addition, the ruthenium centres are bonded to another chloride ligand. The aromatic rings and the Ru(2)Cl(2) four-membered ring enclose a dihedral angle of 55.85 (6)°.

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