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Di-μ(2)-chlorido-bis[chlorido(η(6)-hexamethylbenzene)ruthenium(II)]
Dimeric molecules of the title compound, [Ru(2)Cl(4)(C(12)H(18))(2)], are located on a crystallographic centre of inversion with one molecule in the asymmetric unit. The hexamethylbenzene rings are in an η(6)-coordination to the ruthenium centres, which are bridged by two chloride ligands. In ad...
| Autores principales: | , , , , |
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| Formato: | Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2009
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971002/ https://www.ncbi.nlm.nih.gov/pubmed/21578121 http://dx.doi.org/10.1107/S1600536809041154 |
| _version_ | 1782190522872365056 |
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| author | González-Torres, Yunuem Espinosa-Jalapa, Noel Hernández-Ortega, Simón Le Lagadec, Ronan Morales-Morales, David |
| author_facet | González-Torres, Yunuem Espinosa-Jalapa, Noel Hernández-Ortega, Simón Le Lagadec, Ronan Morales-Morales, David |
| author_sort | González-Torres, Yunuem |
| collection | PubMed |
| description | Dimeric molecules of the title compound, [Ru(2)Cl(4)(C(12)H(18))(2)], are located on a crystallographic centre of inversion with one molecule in the asymmetric unit. The hexamethylbenzene rings are in an η(6)-coordination to the ruthenium centres, which are bridged by two chloride ligands. In addition, the ruthenium centres are bonded to another chloride ligand. The aromatic rings and the Ru(2)Cl(2) four-membered ring enclose a dihedral angle of 55.85 (6)°. |
| format | Text |
| id | pubmed-2971002 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2009 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-29710022010-12-30 Di-μ(2)-chlorido-bis[chlorido(η(6)-hexamethylbenzene)ruthenium(II)] González-Torres, Yunuem Espinosa-Jalapa, Noel Hernández-Ortega, Simón Le Lagadec, Ronan Morales-Morales, David Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers Dimeric molecules of the title compound, [Ru(2)Cl(4)(C(12)H(18))(2)], are located on a crystallographic centre of inversion with one molecule in the asymmetric unit. The hexamethylbenzene rings are in an η(6)-coordination to the ruthenium centres, which are bridged by two chloride ligands. In addition, the ruthenium centres are bonded to another chloride ligand. The aromatic rings and the Ru(2)Cl(2) four-membered ring enclose a dihedral angle of 55.85 (6)°. International Union of Crystallography 2009-10-17 /pmc/articles/PMC2971002/ /pubmed/21578121 http://dx.doi.org/10.1107/S1600536809041154 Text en © González-Torres et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers González-Torres, Yunuem Espinosa-Jalapa, Noel Hernández-Ortega, Simón Le Lagadec, Ronan Morales-Morales, David Di-μ(2)-chlorido-bis[chlorido(η(6)-hexamethylbenzene)ruthenium(II)] |
| title | Di-μ(2)-chlorido-bis[chlorido(η(6)-hexamethylbenzene)ruthenium(II)] |
| title_full | Di-μ(2)-chlorido-bis[chlorido(η(6)-hexamethylbenzene)ruthenium(II)] |
| title_fullStr | Di-μ(2)-chlorido-bis[chlorido(η(6)-hexamethylbenzene)ruthenium(II)] |
| title_full_unstemmed | Di-μ(2)-chlorido-bis[chlorido(η(6)-hexamethylbenzene)ruthenium(II)] |
| title_short | Di-μ(2)-chlorido-bis[chlorido(η(6)-hexamethylbenzene)ruthenium(II)] |
| title_sort | di-μ(2)-chlorido-bis[chlorido(η(6)-hexamethylbenzene)ruthenium(ii)] |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971002/ https://www.ncbi.nlm.nih.gov/pubmed/21578121 http://dx.doi.org/10.1107/S1600536809041154 |
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