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(1S*,4aR*,5S*,6S*,8aR*)-3-Benzyl-1-methyl-5,6-diphenyl-3,4,4a,5,6,8a-hexahydro-1H-2,3-benzoxazin-4-one
In the title compound, C(28)H(27)NO(2), the oxazinone ring adopts a twist-boat conformation and the cyclohexene ring has a twisted envelope conformation. The crystal structure is stabilized by weak non-classical intermolecular C—H⋯O hydrogen bonds.
| Autores principales: | , |
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| Formato: | Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2009
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971003/ https://www.ncbi.nlm.nih.gov/pubmed/21578507 http://dx.doi.org/10.1107/S1600536809044195 |
| _version_ | 1782190523100954624 |
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| author | Wang, Yan Wu, Jin-Long |
| author_facet | Wang, Yan Wu, Jin-Long |
| author_sort | Wang, Yan |
| collection | PubMed |
| description | In the title compound, C(28)H(27)NO(2), the oxazinone ring adopts a twist-boat conformation and the cyclohexene ring has a twisted envelope conformation. The crystal structure is stabilized by weak non-classical intermolecular C—H⋯O hydrogen bonds. |
| format | Text |
| id | pubmed-2971003 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2009 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-29710032010-12-30 (1S*,4aR*,5S*,6S*,8aR*)-3-Benzyl-1-methyl-5,6-diphenyl-3,4,4a,5,6,8a-hexahydro-1H-2,3-benzoxazin-4-one Wang, Yan Wu, Jin-Long Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(28)H(27)NO(2), the oxazinone ring adopts a twist-boat conformation and the cyclohexene ring has a twisted envelope conformation. The crystal structure is stabilized by weak non-classical intermolecular C—H⋯O hydrogen bonds. International Union of Crystallography 2009-10-31 /pmc/articles/PMC2971003/ /pubmed/21578507 http://dx.doi.org/10.1107/S1600536809044195 Text en © Wang and Wu 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Organic Papers Wang, Yan Wu, Jin-Long (1S*,4aR*,5S*,6S*,8aR*)-3-Benzyl-1-methyl-5,6-diphenyl-3,4,4a,5,6,8a-hexahydro-1H-2,3-benzoxazin-4-one |
| title | (1S*,4aR*,5S*,6S*,8aR*)-3-Benzyl-1-methyl-5,6-diphenyl-3,4,4a,5,6,8a-hexahydro-1H-2,3-benzoxazin-4-one |
| title_full | (1S*,4aR*,5S*,6S*,8aR*)-3-Benzyl-1-methyl-5,6-diphenyl-3,4,4a,5,6,8a-hexahydro-1H-2,3-benzoxazin-4-one |
| title_fullStr | (1S*,4aR*,5S*,6S*,8aR*)-3-Benzyl-1-methyl-5,6-diphenyl-3,4,4a,5,6,8a-hexahydro-1H-2,3-benzoxazin-4-one |
| title_full_unstemmed | (1S*,4aR*,5S*,6S*,8aR*)-3-Benzyl-1-methyl-5,6-diphenyl-3,4,4a,5,6,8a-hexahydro-1H-2,3-benzoxazin-4-one |
| title_short | (1S*,4aR*,5S*,6S*,8aR*)-3-Benzyl-1-methyl-5,6-diphenyl-3,4,4a,5,6,8a-hexahydro-1H-2,3-benzoxazin-4-one |
| title_sort | (1s*,4ar*,5s*,6s*,8ar*)-3-benzyl-1-methyl-5,6-diphenyl-3,4,4a,5,6,8a-hexahydro-1h-2,3-benzoxazin-4-one |
| topic | Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971003/ https://www.ncbi.nlm.nih.gov/pubmed/21578507 http://dx.doi.org/10.1107/S1600536809044195 |
| work_keys_str_mv | AT wangyan 1s4ar5s6s8ar3benzyl1methyl56diphenyl344a568ahexahydro1h23benzoxazin4one AT wujinlong 1s4ar5s6s8ar3benzyl1methyl56diphenyl344a568ahexahydro1h23benzoxazin4one |