Bis[2-(1H-1,2,4-triazol-1-yl-κN (2))-1,10-phenanthroline-κ(2) N,N′]zinc(II) bis­(perchlorate)

In the title complex, [Zn(C(14)H(9)N(5))(2)](ClO(4))(2), 2-(1H-1,2,4-triazol-1-yl)-1,10-phenanthroline functions as a tridentate ligand and the Zn(II) ion assumes a distorted octa­hedral ZnN(6) coordination geometry. There is a weak π–π stacking inter­action between symmetry-related triazolyl rings...

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Detalles Bibliográficos
Autores principales: Xie, Long Miao, Meng, Lin, Shi, Jing Min
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971005/
https://www.ncbi.nlm.nih.gov/pubmed/21578050
http://dx.doi.org/10.1107/S160053680903877X
Descripción
Sumario:In the title complex, [Zn(C(14)H(9)N(5))(2)](ClO(4))(2), 2-(1H-1,2,4-triazol-1-yl)-1,10-phenanthroline functions as a tridentate ligand and the Zn(II) ion assumes a distorted octa­hedral ZnN(6) coordination geometry. There is a weak π–π stacking inter­action between symmetry-related triazolyl rings with a centroid–centroid distance of 3.802 (4) Å and a perpendicular distance of 3.413 Å between the rings.

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