Bis[2-(1H-1,2,4-triazol-1-yl-κN (2))-1,10-phenanthroline-κ(2) N,N′]zinc(II) bis­(perchlorate)

In the title complex, [Zn(C(14)H(9)N(5))(2)](ClO(4))(2), 2-(1H-1,2,4-triazol-1-yl)-1,10-phenanthroline functions as a tridentate ligand and the Zn(II) ion assumes a distorted octa­hedral ZnN(6) coordination geometry. There is a weak π–π stacking inter­action between symmetry-related triazolyl rings...

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Detalles Bibliográficos
Autores principales: Xie, Long Miao, Meng, Lin, Shi, Jing Min
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971005/
https://www.ncbi.nlm.nih.gov/pubmed/21578050
http://dx.doi.org/10.1107/S160053680903877X
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author Xie, Long Miao
Meng, Lin
Shi, Jing Min
author_facet Xie, Long Miao
Meng, Lin
Shi, Jing Min
author_sort Xie, Long Miao
collection PubMed
description In the title complex, [Zn(C(14)H(9)N(5))(2)](ClO(4))(2), 2-(1H-1,2,4-triazol-1-yl)-1,10-phenanthroline functions as a tridentate ligand and the Zn(II) ion assumes a distorted octa­hedral ZnN(6) coordination geometry. There is a weak π–π stacking inter­action between symmetry-related triazolyl rings with a centroid–centroid distance of 3.802 (4) Å and a perpendicular distance of 3.413 Å between the rings.
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spelling pubmed-29710052010-12-30 Bis[2-(1H-1,2,4-triazol-1-yl-κN (2))-1,10-phenanthroline-κ(2) N,N′]zinc(II) bis­(perchlorate) Xie, Long Miao Meng, Lin Shi, Jing Min Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title complex, [Zn(C(14)H(9)N(5))(2)](ClO(4))(2), 2-(1H-1,2,4-triazol-1-yl)-1,10-phenanthroline functions as a tridentate ligand and the Zn(II) ion assumes a distorted octa­hedral ZnN(6) coordination geometry. There is a weak π–π stacking inter­action between symmetry-related triazolyl rings with a centroid–centroid distance of 3.802 (4) Å and a perpendicular distance of 3.413 Å between the rings. International Union of Crystallography 2009-10-03 /pmc/articles/PMC2971005/ /pubmed/21578050 http://dx.doi.org/10.1107/S160053680903877X Text en © Xie et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Xie, Long Miao
Meng, Lin
Shi, Jing Min
Bis[2-(1H-1,2,4-triazol-1-yl-κN (2))-1,10-phenanthroline-κ(2) N,N′]zinc(II) bis­(perchlorate)
title Bis[2-(1H-1,2,4-triazol-1-yl-κN (2))-1,10-phenanthroline-κ(2) N,N′]zinc(II) bis­(perchlorate)
title_full Bis[2-(1H-1,2,4-triazol-1-yl-κN (2))-1,10-phenanthroline-κ(2) N,N′]zinc(II) bis­(perchlorate)
title_fullStr Bis[2-(1H-1,2,4-triazol-1-yl-κN (2))-1,10-phenanthroline-κ(2) N,N′]zinc(II) bis­(perchlorate)
title_full_unstemmed Bis[2-(1H-1,2,4-triazol-1-yl-κN (2))-1,10-phenanthroline-κ(2) N,N′]zinc(II) bis­(perchlorate)
title_short Bis[2-(1H-1,2,4-triazol-1-yl-κN (2))-1,10-phenanthroline-κ(2) N,N′]zinc(II) bis­(perchlorate)
title_sort bis[2-(1h-1,2,4-triazol-1-yl-κn (2))-1,10-phenanthroline-κ(2) n,n′]zinc(ii) bis­(perchlorate)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971005/
https://www.ncbi.nlm.nih.gov/pubmed/21578050
http://dx.doi.org/10.1107/S160053680903877X
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AT menglin bis21h124triazol1ylkn2110phenanthrolinek2nnzinciibisperchlorate
AT shijingmin bis21h124triazol1ylkn2110phenanthrolinek2nnzinciibisperchlorate

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